Ontology highlight
ABSTRACT:
SUBMITTER: Ni S
PROVIDER: S-EPMC6598763 | biostudies-literature | 2019 Jun
REPOSITORIES: biostudies-literature
Science advances 20190628 6
The reductive cross-coupling of sp<sup>3</sup>-hybridized carbon centers represents great synthetic values and insurmountable challenges. In this work, we report a nickel-catalyzed deaminative cross-electrophile coupling reaction to construct C(sp)─C(sp<sup>3</sup>), C(sp<sup>2</sup>)─C(sp<sup>3</sup>), and C(sp<sup>3</sup>)─C(sp<sup>3</sup>) bonds. A wide range of coupling partners including aryl iodides, bromoalkynes, or alkyl bromides are stitched with alkylpyridinium salts that derived from ...[more]