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Quaternized cellulose and graphene oxide crosslinked polyphenylene oxide based anion exchange membrane.

ABSTRACT: Anion exchange membrane fuel cells (AEMFCs) have captivated vast interest due to non-platinum group metal catalysts and fuel flexibility. One of the major shortcomings of AEMFCs, however, is the lack of a stable and high anion conducting membrane. This study introduces a new strategy for fabrication of high conducting anion exchange membrane (AEM) using a hybrid nanocomposite of graphene oxide (GO), cellulose, and poly(phenylene oxide) (PPO), which are functionalized with 1,4-diazabicyclo[2.2.2]octane. The compositional ratio of GO/cellulose/PPO was optimized with respect to ionic conductivity, water uptake, swelling ratio, and mechanical properties. The membrane at GO/cellulose/PPO weight ratio of 1/1/100 displayed an impressive hydroxyl conductivity of ?114 mS/cm at 25?°C and ?215 mS/cm at 80?°C, which is considerably higher than the highest value reported. Further, the hybrid composite membranes were mechanically stable even when operating at high temperature (80?°C). The result indicates that the introduction of quaternized GO and cellulose into a polymer matrix is a promising approach for designing high performance AEMs.

SUBMITTER: Das G

PROVIDER: S-EPMC6606628 | biostudies-literature | 2019 Jul

REPOSITORIES: biostudies-literature

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Quaternized cellulose and graphene oxide crosslinked polyphenylene oxide based anion exchange membrane.

Das Gautam G Park Bang Ju BJ Kim Jihyeon J Kang Dongho D Yoon Hyon Hee HH

Scientific reports 20190702 1

Anion exchange membrane fuel cells (AEMFCs) have captivated vast interest due to non-platinum group metal catalysts and fuel flexibility. One of the major shortcomings of AEMFCs, however, is the lack of a stable and high anion conducting membrane. This study introduces a new strategy for fabrication of high conducting anion exchange membrane (AEM) using a hybrid nanocomposite of graphene oxide (GO), cellulose, and poly(phenylene oxide) (PPO), which are functionalized with 1,4-diazabicyclo[2.2.2] ...[more]

PMID: 31266980

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Project description:This Review provides an overview of the emerging concepts of catalysts, membranes, and membrane electrode assemblies (MEAs) for water electrolyzers with anion-exchange membranes (AEMs), also known as zero-gap alkaline water electrolyzers. Much of the recent progress is due to improvements in materials chemistry, MEA designs, and optimized operation conditions. Research on anion-exchange polymers (AEPs) has focused on the cationic head/backbone/side-chain structures and key properties such as ionic conductivity and alkaline stability. Several approaches, such as cross-linking, microphase, and organic/inorganic composites, have been proposed to improve the anion-exchange performance and the chemical and mechanical stability of AEMs. Numerous AEMs now exceed values of 0.1 S/cm (at 60-80 °C), although the stability specifically at temperatures exceeding 60 °C needs further enhancement. The oxygen evolution reaction (OER) is still a limiting factor. An analysis of thin-layer OER data suggests that NiFe-type catalysts have the highest activity. There is debate on the active-site mechanism of the NiFe catalysts, and their long-term stability needs to be understood. Addition of Co to NiFe increases the conductivity of these catalysts. The same analysis for the hydrogen evolution reaction (HER) shows carbon-supported Pt to be dominating, although PtNi alloys and clusters of Ni(OH)2 on Pt show competitive activities. Recent advances in forming and embedding well-dispersed Ru nanoparticles on functionalized high-surface-area carbon supports show promising HER activities. However, the stability of these catalysts under actual AEMWE operating conditions needs to be proven. The field is advancing rapidly but could benefit through the adaptation of new in situ techniques, standardized evaluation protocols for AEMWE conditions, and innovative catalyst-structure designs. Nevertheless, single AEM water electrolyzer cells have been operated for several thousand hours at temperatures and current densities as high as 60 °C and 1 A/cm2, respectively.

Dataset Information

Quaternized cellulose and graphene oxide crosslinked polyphenylene oxide based anion exchange membrane.

Publications

Quaternized cellulose and graphene oxide crosslinked polyphenylene oxide based anion exchange membrane.

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