Free-Radical Polymerization of Acrylic Acid under Extreme Reaction Conditions Mimicking Deep-Sea Hydrothermal Vents.
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ABSTRACT:
SUBMITTER: Kinoshita K
PROVIDER: S-EPMC6641060 | biostudies-literature | 2017 Jun
REPOSITORIES: biostudies-literature
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Free-Radical Polymerization of Acrylic Acid under Extreme Reaction Conditions Mimicking Deep-Sea Hydrothermal Vents.
Kinoshita Keigo K Takano Yoshinori Y Ohkouchi Naohiko N Deguchi Shigeru S
ACS omega 20170619 6
Free-radical polymerization with a thermochemical initiator, which usually takes hours to complete, was dramatically accelerated under reaction conditions mimicking the deep-sea hydrothermal vents, where reaction mixtures were only briefly exposed to ultrahigh temperatures under pressure. In tests using acrylic acid and potassium persulfate, poly(acrylic acid) (<i>M</i> <sub>n</sub> = 2.1 × 10<sup>4</sup>, <i>Đ</i> = 2.73) was obtained in 5.2 s with the monomer conversion of 60.3% in water at 20 ...[more]
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