Ionic Liquid-Based Electrolytes Containing Surface-Functionalized Inorganic Nanofibers for Quasisolid Lithium Batteries.

ABSTRACT: In the present study, surface amino-functionalized silica nanofibers (f-SiO₂NFs, average diameter = 400 and 1000 nm) are used as one-dimensional (1-D) fillers of ionic liquid (IL)-based quasisolid electrolytes. On adding f-SiO₂NFs to an IL (1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)amide, EMITFSA) containing lithium bis(trifluoromethanesulfonyl)-amide (LiTFSA), the well-dispersed 1-D nanofillers easily form a three-dimensional network structure in the IL, function as physical cross-linkers, and increase the viscosity of the composites, consequently providing a quasisolid state at a 3.5 wt % fraction of the NFs. Rheological measurements demonstrate that the prepared composites exhibit "gel-like" characteristics at 40-150 °C. All prepared composites show high ionic conductivities, on the order of 10^-3 S cm^-1, around room temperature. To investigate the additive effect of f-SiO₂NFs in the composites, the lithium transference numbers are also evaluated. It is found that thinner NFs enhance the transference numbers of the composites. In addition, quasisolid lithium-ion cells containing the prepared composites demonstrate relatively high rate characteristics and good cycling performance at high temperature (125 °C).

SUBMITTER: Yuuki T 

PROVIDER: S-EPMC6641074 | biostudies-literature | 2017 Mar

REPOSITORIES: biostudies-literature