Dataset Information

Preparation of Cellulose Nanocrystal-Reinforced Poly(lactic acid) Nanocomposites through Noncovalent Modification with PLLA-Based Surfactants.

ABSTRACT: Cellulose nanocrystal (CNC)-reinforced poly(lactic acid) (PLA) nanocomposites were prepared by twin-screw extrusion followed by injection-molding using a masterbatch approach. Noncovalent modification of CNCs was performed with two different poly(l-lactide) (PLLA)-based surfactants to improve the filler/matrix compatibility. They both have a PLLA block that is expected to improve the compatibility with the PLA matrix and differ by the polar head. It consists of either a poly(ethylene glycol) (PEG) block (PEG-b-PLLA) or an imidazolium group (Im-PLLA), that is able to interact with the surface of the CNCs. The morphological, structural, thermal, rheological, and mechanical properties of the nanocomposites were investigated. The different modes of interaction of the polar head of the surfactant lead to different properties. However, the global decrease in the molecular weight of PLA, induced by the short PLLA blocks from the surfactants and the possible degradation during melt processing, results in a plasticization effect and impacts the crystallization of the matrix.

SUBMITTER: Mariano M

PROVIDER: S-EPMC6641156 | biostudies-literature | 2017 Jun

REPOSITORIES: biostudies-literature

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Preparation of Cellulose Nanocrystal-Reinforced Poly(lactic acid) Nanocomposites through Noncovalent Modification with PLLA-Based Surfactants.

Mariano Marcos M Pilate Florence F de Oliveira Franciéli Borges FB Khelifa Farid F Dubois Philippe P Raquez Jean-Marie JM Dufresne Alain A

ACS omega 20170616 6

Cellulose nanocrystal (CNC)-reinforced poly(lactic acid) (PLA) nanocomposites were prepared by twin-screw extrusion followed by injection-molding using a masterbatch approach. Noncovalent modification of CNCs was performed with two different poly(l-lactide) (PLLA)-based surfactants to improve the filler/matrix compatibility. They both have a PLLA block that is expected to improve the compatibility with the PLA matrix and differ by the polar head. It consists of either a poly(ethylene glycol) (PE ...[more]

PMID: 31457609

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Project description:3D-printed bone scaffolds hold great promise for the individualized treatment of critical-size bone defects. Among the resorbable polymers available for use as 3D-printable scaffold materials, poly(ε-caprolactone) (PCL) has many benefits. However, its relatively low stiffness and lack of bioactivity limit its use in load-bearing bone scaffolds. This study tests the hypothesis that surface-oxidized cellulose nanocrystals (SO-CNCs), decorated with carboxyl groups, can act as multi-functional scaffold additives that (1) improve the mechanical properties of PCL and (2) induce biomineral formation upon PCL resorption. To this end, an in vitro biomineralization study was performed to assess the ability of SO-CNCs to induce the formation of calcium phosphate minerals. In addition, PCL nanocomposites containing different amounts of SO-CNCs (1, 2, 3, 5, and 10 wt%) were prepared using melt compounding extrusion and characterized in terms of Young's modulus, ultimate tensile strength, crystallinity, thermal transitions, and water contact angle. Neither sulfuric acid-hydrolyzed CNCs (SH-CNCs) nor SO-CNCs were toxic to MC3T3 preosteoblasts during a 24 h exposure at concentrations ranging from 0.25 to 3.0 mg/mL. SO-CNCs were more effective at inducing mineral formation than SH-CNCs in simulated body fluid (1x). An SO-CNC content of 10 wt% in the PCL matrix caused a more than 2-fold increase in Young's modulus (stiffness) and a more than 60% increase in ultimate tensile strength. The matrix glass transition and melting temperatures were not affected by the SO-CNCs but the crystallization temperature increased by about 5.5°C upon addition of 10 wt% SO-CNCs, the matrix crystallinity decreased from about 43 to about 40%, and the water contact angle decreased from 87 to 82.6°. The abilities of SO-CNCs to induce calcium phosphate mineral formation and increase the Young's modulus of PCL render them attractive for applications as multi-functional nanoscale additives in PCL-based bone scaffolds.

Dataset Information

Preparation of Cellulose Nanocrystal-Reinforced Poly(lactic acid) Nanocomposites through Noncovalent Modification with PLLA-Based Surfactants.

Publications

Preparation of Cellulose Nanocrystal-Reinforced Poly(lactic acid) Nanocomposites through Noncovalent Modification with PLLA-Based Surfactants.

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