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Formation of TbPc₂ Single-Molecule Magnets' Covalent 1D Structures via Acyclic Diene Metathesis.

ABSTRACT: We present here a reaction scheme to connect TbPc₂ single-molecule magnets into 1D architectures using acyclic diene metathesis. To investigate the impact of the bonding through aliphatic chains on the magnetic properties of TbPc₂, we isolate and characterize the dimeric species obtained as one of the products of the reaction. Remarkably, the magnetic properties are only slightly modified after the formation of the bond between molecules, enlightening the great potential of this reaction scheme.

SUBMITTER: Pedrini A

PROVIDER: S-EPMC6641184 | biostudies-literature | 2017 Feb

REPOSITORIES: biostudies-literature

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Formation of TbPc2 Single-Molecule Magnets' Covalent 1D Structures via Acyclic Diene Metathesis.

Pedrini Alessandro A Perfetti Mauro M Mannini Matteo M Dalcanale Enrico E

ACS omega 20170213 2

We present here a reaction scheme to connect TbPc2 single-molecule magnets into 1D architectures using acyclic diene metathesis. To investigate the impact of the bonding through aliphatic chains on the magnetic properties of TbPc2, we isolate and characterize the dimeric species obtained as one of the products of the reaction. Remarkably, the magnetic properties are only slightly modified after the formation of the bond between molecules, enlightening the great potential of ...[more]

PMID: 31457452

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