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Easily Processable Temperature-Responsive Infrared-Reflective Polymer Coatings.

ABSTRACT: A temperature-responsive near-infrared reflective coating was fabricated based on a side-chain liquid crystal siloxane polymer using a simple wired-bar method. The cholesteric liquid crystalline polymer film showed a blue shift of the reflection band of ?1000 nm in the IR region upon heating. The temperature-responsive change of the reflection band was reversible. Compared to that of the same mixture system in an alignment cell, the coating showed a significantly faster response. This research demonstrates an easy way to prepare a temperature-responsive IR-reflective coating that shifts its reflection to a shorter wavelength upon heating. As IR radiation of shorter wavelengths is more strongly represented in sunlight than longer wavelengths, this coating could be used to selectively reduce heating of an indoor space when the temperature is high. This is promising for the future application of smart climate control.

SUBMITTER: Zhang W

PROVIDER: S-EPMC6641380 | biostudies-literature | 2017 Jul

REPOSITORIES: biostudies-literature

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Easily Processable Temperature-Responsive Infrared-Reflective Polymer Coatings.

Zhang Weixin W Kragt Stijn S Schenning Albertus P H J APHJ de Haan Laurens T LT Zhou Guofu G

ACS omega 20170712 7

A temperature-responsive near-infrared reflective coating was fabricated based on a side-chain liquid crystal siloxane polymer using a simple wired-bar method. The cholesteric liquid crystalline polymer film showed a blue shift of the reflection band of ∼1000 nm in the IR region upon heating. The temperature-responsive change of the reflection band was reversible. Compared to that of the same mixture system in an alignment cell, the coating showed a significantly faster response. This research d ...[more]

PMID: 31457669

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Project description:Novel brush coatings were fabricated with glass surface-grafted chains copolymerized using surface-initiated atom transfer radical polymerization (SI-ATRP) from 2-(2-methoxyethoxy)ethyl methacrylate (OEGMA188) and acrylamide (AAm), taken in different proportions. P(OEGMA188-co-AAm) brushes with AAm mole fraction >44% (determined with XPS and TOF-SIMS spectroscopy) and nearly constant with the depth copolymer composition (TOF-SIMS profiling) exhibit unusual temperature-induced transformations: The contact angle of water droplets on P(OEGMA188-co-AAm) coatings increases by ∼45° with temperature, compared to 17-18° for POEGMA188 and PAAm. The thickness of coatings immersed in water and the morphology of coatings imaged in air show a temperature response for POEGMA188 (using reflectance spectroscopy and AFM, respectively), but this response is weak for P(OEGMA188-co-AAm) and absent for PAAm. This suggests mechanisms more complex than a simple transition between hydrated loose coils and hydrophobic collapsed chains. For POEGMA188, the hydrogen bonds between the ether oxygens of poly(ethylene glycol) and water hydrogens are formed below the transition temperature Tc and disrupted above Tc when polymer-polymer interactions are favored. Different hydrogen bond structures of PAAm include free amide groups, cis-trans-multimers, and trans-multimers of amide groups. Here, hydrogen bonds between free amide groups and water dominate at T < Tc but structures favored at T > Tc, such as cis-trans-multimers and trans-multimers of amide groups, can still be hydrated. The enhanced temperature-dependent response of wettability for P(OEGMA188-co-AAm) with a high mole fraction of AAm suggests the formation at Tc of more hydrophobic structures, realized by hydrogen bonding between the ether oxygens of OEGMA188 and the amide fragments of AAm, where water molecules are caged. Furthermore, P(OEGMA188-co-AAm) coatings immersed in pH buffer solutions exhibit a 'schizophrenic' behavior in wettability, with transitions that mimic LCST and UCST for pH = 3, LCST for pH = 5 and 7, and any transition blocked for pH = 9.

Dataset Information

Easily Processable Temperature-Responsive Infrared-Reflective Polymer Coatings.

Publications

Easily Processable Temperature-Responsive Infrared-Reflective Polymer Coatings.

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