Ontology highlight
ABSTRACT:
SUBMITTER: Pearce N
PROVIDER: S-EPMC6644668 | biostudies-literature | 2018 Oct
REPOSITORIES: biostudies-literature
ACS omega 20181026 10
Perylene diimides (PDIs) are promising candidates for n-type semiconductor materials and, thus, for use in organic electronics. Thionation of the imide moiety provides an efficient strategy to control the donor-acceptor gap of these types of compounds, although the degree and selectivity of thionation can be hard to achieve. Through the design of a sterically encumbered PDI-phenothiazine dyad, a previously unattained geminal thionation pattern has been realized, providing the first example of a ...[more]