Structure Evolution from Layered to Spinel during Synthetic Control and Cycling Process of Fe-Containing Li-Rich Cathode Materials for Lithium-Ion Batteries.

ABSTRACT: As promising cathode materials for lithium-ion batteries (LIBs), Fe-containing Li-rich compounds of Li_1+x Fe_0.1Ni_0.15Mn_0.55O _y (0 ? x ? 0.3 and 1.9 ? y ? 2.05) have been successfully synthesized by calcining the spherical precursors with appropriate amounts of lithium carbonate. The structures, morphologies, and chemical states of these compounds are characterized to better understand the corresponding electrochemical performances. With an increase of lithium content, Li_1+x Fe_0.1Ni_0.15Mn_0.55O _y evolves from a complex layered-spinel structure to a layered structure. The lithium content also affects the average size and adhesion of the primary particles. At 0.1 C, sample x = 0.1 shows the highest first charge/discharge specific capacities (338.7 and 254.3 mA h g^-1), the highest first Coulombic efficiency (75.1%), the lowest first irreversible capacity loss (84.4 mA h g^-1), the highest reversible discharge specific capacity, and good rate capability. Notably, voltage fading can be alleviated through the adjustment of structural features. Such superior electrochemical performances of sample x = 0.1 are ascribed to the hierarchical micro-/nanostructure, the harmonious existence of complex layered-spinel phase, and the low charge-transfer resistance. An integral view of structure evolution from layered to spinel during synthetic control and cycling process is provided to broaden the performance scope of Li-Fe-Ni-Mn-O cathodes for LIBs.

SUBMITTER: Zhao T 

PROVIDER: S-EPMC6644733 | biostudies-literature | 2017 Sep

REPOSITORIES: biostudies-literature