Efficient Cleavage of Permethylated Cyclodextrins.
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ABSTRACT:
SUBMITTER: Ishida Y
PROVIDER: S-EPMC6644737 | biostudies-literature | 2018 Jun
REPOSITORIES: biostudies-literature
Publications
Efficient Cleavage of Permethylated Cyclodextrins.
ACS omega 20180611 6
The cleavage of a permethylated α-cyclodextrin, that is, purity and chemical yield of a maltohexaose derivative thus obtained, was decisively affected by the reaction time. The matrix-assisted laser desorption ionization time-of-flight mass spectrometry spectra with synthetic data enable us to improve the cleavage reaction more efficiently. The optimized conditions developed in the present study allow us to cleave the permethylated γ-cyclodextrin to afford a maltooctaose derivative as a new synt ...[more]
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