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Toward Rational Design of Ionic Liquid/Metal-Organic Framework Composites: Effects of Interionic Interaction Energy.

ABSTRACT: One of the structural factors controlling the extent of interactions between ionic liquids (ILs) and metal-organic frameworks (MOFs) in IL/MOF composites is elucidated. Results showed that the thermal stability limits and adsorption performances of the IL/MOF composites can be tuned by the interionic interaction energy of bulk ILs, which can be probed spectroscopically via C2H infrared stretching frequency.

SUBMITTER: Nozari V

PROVIDER: S-EPMC6644886 | biostudies-literature | 2017 Oct

REPOSITORIES: biostudies-literature

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Toward Rational Design of Ionic Liquid/Metal-Organic Framework Composites: Effects of Interionic Interaction Energy.

Nozari Vahid V Keskin Seda S Uzun Alper A

ACS omega 20171011 10

One of the structural factors controlling the extent of interactions between ionic liquids (ILs) and metal-organic frameworks (MOFs) in IL/MOF composites is elucidated. Results showed that the thermal stability limits and adsorption performances of the IL/MOF composites can be tuned by the interionic interaction energy of bulk ILs, which can be probed spectroscopically via C2H infrared stretching frequency. ...[more]

PMID: 31457258

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