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New Lutetium Oxide: Electrically Conducting Rock-Salt LuO Epitaxial Thin Film.


ABSTRACT: C-rare earth structure lutetium sesquioxide Lu2O3 has been recognized as a high-k widegap insulator with closed shell Lu3+ ions. In this study, rock-salt structure lutetium monoxide LuO with unusual valence of Lu2+ (4f145d1), previously known as the gaseous phase, was synthesized as an epitaxial thin film by the pulsed laser deposition method. In contrast with transparent and highly insulating Lu2O3, LuO possessed a dark-brown color and high electrical conductivity concomitant with strong spin-orbit coupling as a manifestation of Lu 5d electron carriers.

SUBMITTER: Kaminaga K 

PROVIDER: S-EPMC6644888 | biostudies-literature | 2018 Oct

REPOSITORIES: biostudies-literature

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New Lutetium Oxide: Electrically Conducting Rock-Salt LuO Epitaxial Thin Film.

Kaminaga Kenichi K   Oka Daichi D   Hasegawa Tetsuya T   Fukumura Tomoteru T  

ACS omega 20181003 10


C-rare earth structure lutetium sesquioxide Lu<sub>2</sub>O<sub>3</sub> has been recognized as a high-<i>k</i> widegap insulator with closed shell Lu<sup>3+</sup> ions. In this study, rock-salt structure lutetium monoxide LuO with unusual valence of Lu<sup>2+</sup> (4f<sup>14</sup>5d<sup>1</sup>), previously known as the gaseous phase, was synthesized as an epitaxial thin film by the pulsed laser deposition method. In contrast with transparent and highly insulating Lu<sub>2</sub>O<sub>3</sub>, L  ...[more]

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