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Room-Temperature Activation of CO2 by Dual Defect-Stabilized Nanoscale Hematite (Fe2-?O3-v ): Concurrent Role of Fe and O Vacancies.


ABSTRACT: We demonstrate that synthetically controlled concurrent stabilization of Fe and O vacancy defects on the surface of interbraided nanoscale hematite (Fe2-?O3-v ) renders an interesting surface chemistry which can reduce CO2 to CO at room temperature (RT). Importantly, we realized a highly enhanced output of 410 ?mol h-1 g-1 at RT, as compared to that of 10 ?mol h-1 g-1 for bulk hematite. It is argued based on the activity degradation under cycling and first principles density functional theory calculations that the excess chemical energy embedded in the defect-stabilized surface is expended in this high-energy conversion process, which leads to progressive filling up of oxygen vacancies.

SUBMITTER: Nagaraju D 

PROVIDER: S-EPMC6645434 | biostudies-literature | 2017 Nov

REPOSITORIES: biostudies-literature

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Room-Temperature Activation of CO<sub>2</sub> by Dual Defect-Stabilized Nanoscale Hematite (Fe<sub>2-δ</sub>O<sub>3-<i>v</i></sub> ): Concurrent Role of Fe and O Vacancies.

Nagaraju Divya D   Gupta Sharad S   Kumar Deepak D   Jijil Chamundi P CP   Bhat Suresh K SK   Jagadeesan Dinesh D   Ogale Satishchandra S  

ACS omega 20171129 11


We demonstrate that synthetically controlled concurrent stabilization of Fe and O vacancy defects on the surface of interbraided nanoscale hematite (Fe<sub>2-δ</sub>O<sub>3-<i>v</i></sub> ) renders an interesting surface chemistry which can reduce CO<sub>2</sub> to CO at room temperature (RT). Importantly, we realized a highly enhanced output of 410 μmol h<sup>-1</sup> g<sup>-1</sup> at RT, as compared to that of 10 μmol h<sup>-1</sup> g<sup>-1</sup> for bulk hematite. It is argued based on the  ...[more]

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