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Luminescent Iridium(III) Chemosensor for Tandem Detection of F- and Al3.

ABSTRACT: A new highly sensitive luminescent iridium(III) chemosensor, 1, was designed and synthesized for tandem detection of fluoride ions (F-) and aluminum ions (Al3+). This sensor 1 exhibited obvious luminesce quenching by hydrogen bond interactions with F-. In addition, the resulting 1-F complex can be further used to detect Al3+ through a luminesce enhancement. The detection limit (0.02 ?M) of 1-F for Al3+ is far lower than the World Health Organization (7.41 ?M) limit for drinking water. Importantly, chemosensor 1-F could be used to detect and quantify F- and Al3+ reversibly. This sensor achieved rapid detection of two ions, which relies on only one probe.

SUBMITTER: Liu JB

PROVIDER: S-EPMC6645507 | biostudies-literature | 2017 Dec

REPOSITORIES: biostudies-literature

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Luminescent Iridium(III) Chemosensor for Tandem Detection of F- and Al3.

Liu Jin-Biao JB Wang Wanhe W Li Guodong G Wang Rui-Xiang RX Leung Chung-Hang CH Ma Dik-Lung DL

ACS omega 20171221 12

A new highly sensitive luminescent iridium(III) chemosensor, 1, was designed and synthesized for tandem detection of fluoride ions (F-) and aluminum ions (Al3+). This sensor 1 exhibited obvious luminesce quenching by hydrogen bond interactions with F-. In addition, the resulting 1-F complex can be further used to detect Al3+ through a luminesce enhancement. The detection limit (0.02 μM) of 1-F for Al3+ is far lowe ...[more]

PMID: 31457433

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