Dataset Information

Long-Term Underwater Hydrophobicity: Exploring Topographic and Chemical Requirements.

ABSTRACT: A family of hybrid organoinorganic silica-based particles with varied chemical natures and morphologies has been synthesized to test their ability to develop coatings with underwater hydrophobicity. The particles were characterized by elemental microanalysis, scanning electron microscopy, and dynamic light scattering to evaluate the organic content, observe the morphology, and estimate the aggregate size, respectively. These morphologies were transferred into surface topographies by spraycoating dispersions made from the particles onto glass supports, resulting in coatings with an ample range of profiles and roughness but all of them being superhydrophobic. Atomic force microscopy and optical profilometry were used to map the coating surfaces and analyze the topography. Then, underwater hydrophobicity endurance was tested by immersion under a 2 cm 20 °C water column perpendicular to circular glass supports coated with the particles. The so-called mirror effect derived from the occurrence of the primary plastron (continuous air layer occluded between the surface and the water) was observed on the surface of all of the coatings tested. Apart from the dependency of plastrons on the water temperature and substrate shape, the plastron quality and lifetime is notably different depending on the particle morphology and thus on the coating topography. These experiments have demonstrated that the most persistent mirror effects, and therefore underwater superhydrophobicity, were produced on coatings that exhibited the smoothest topographies at the micrometric scale. In addition, these particle-only coatings can be made mechanically stable and robust by blending with a polymer matrix.

SUBMITTER: Martinez-Gomez A

PROVIDER: S-EPMC6645558 | biostudies-literature | 2017 Dec

REPOSITORIES: biostudies-literature

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Long-Term Underwater Hydrophobicity: Exploring Topographic and Chemical Requirements.

Martínez-Gómez Aránzazu A López Silvia S García Teresa T de Francisco Raquel R Tiemblo Pilar P García Nuria N

ACS omega 20171213 12

A family of hybrid organoinorganic silica-based particles with varied chemical natures and morphologies has been synthesized to test their ability to develop coatings with underwater hydrophobicity. The particles were characterized by elemental microanalysis, scanning electron microscopy, and dynamic light scattering to evaluate the organic content, observe the morphology, and estimate the aggregate size, respectively. These morphologies were transferred into surface topographies by spraycoating ...[more]

PMID: 31457420

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Project description:The aim of this study was to assess the short- and long-term effects of resistance training (RT) with different stability requirements. Fifty-nine men underwent a 3-week familiarization period followed by a 7-week training period. During familiarization, all participants trained four sessions of squats with a Smith machine, free weights and free weights standing on a wobble board. After week-3, participants were randomized into a low (Smith machine), medium (Free-weight) or high (Wobble board) stability RT program, and Control group. All participants were tested pre-, after week-3 and post-intervention. Ten repetition maximum (10RM), rate of force development (RFD), electromyography (EMG) and maximum voluntary isometric contraction (MVIC) were tested in all three squat conditions in addition to countermovement jump (CMJ) on stable and unstable surfaces, and muscle thickness. After familiarization, greater 10RM loads (21.8-27.3%), MVIC (7.4-13.5%), RFD (29.7-43.8%) and CMJ (4.9-8.5%) were observed in all conditions. Between week 3 and 10, the Free-weight and Wobble board groups similarly improved 10RM in all conditions. Smith machine group demonstrated greater improvement in the trained exercise than the medium and high stability exercises. All training groups showed similar improvement in muscle thickness, RFD and MVIC. There was no CMJ improvement on the stable surface, but the Wobble board group demonstrated significantly greater improvement on the unstable surface. In conclusion, low, medium or high stability RT resulted in similar improvements in trained and non-trained testing conditions except for greater CMJ on the unstable surface in the Wobble group. Greater 10RM strength in trained than non-trained exercise was only observed in low stability group. Familiarization was associated with substantial improvements in 10RM and CMJ, with greater improvement associated with higher stability requirements. These findings suggest that high stability can increase strength, muscle thickness and explosive measurements similar to training with lower stability.

Dataset Information

Long-Term Underwater Hydrophobicity: Exploring Topographic and Chemical Requirements.

Publications

Long-Term Underwater Hydrophobicity: Exploring Topographic and Chemical Requirements.

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