Tuning Ni-Foam into NiOOH/FeOOH Heterostructures toward Superior Water Oxidation Catalyst via Three-Step Strategy.

ABSTRACT: Splitting of water into hydrogen and oxygen has become a strategic research topic. In the two semi-reactions of water splitting, water oxidation is preferred to the four-electron-transfer process with a higher overpotential (?) and is the decisive step in water splitting. Therefore, efficient water oxidation catalysts must be developed. IrO _x and RuO _x catalysts are currently the most efficient catalysts in water oxidation. However, the limited reserve and high prices of precious metals, such as Ir and Ru, limit future large-scale industrial production of water oxidation catalysts. In this study, we tune inert Ni-foam into highly active NiOOH/FeOOH heterostructures as water oxidation catalysts via three-step strategy (surface acid-treating, electroplating, and electrooxidation). NiOOH/FeOOH heterostructures as water oxidation catalysts only require ? of 257 mV to reach a current density of 10 mA cm^-2, which is superior to that of IrO₂/Ni-foam (280 mV). The high electrochemically active surface area (72.50 cm²) and roughness factor demonstrate abundant interfaces in NiOOH/FeOOH heterostructures, thus accelerating water oxidation activity. The small value (4.8 ? cm²) of charge transfer resistance (R _ct) indicate that fast electronic exchange occurs between NiOOH/FeOOH heterostructures catalyst and reaction of water oxidation. Hydrogen-to-oxygen volume ratios (approximately 2:1) indicate an almost overall water splitting by the double-electrode system. Faraday efficiency of H₂ or O₂ is close to 90% at 2:1 hydrogen-to-oxygen volume ratio. NiOOH/FeOOH heterostructures exhibit good stability. The results provide significance in fundamental research and practical applications in solar water splitting, artificial photoelectrochemical cells, and electrocatalysts.

SUBMITTER: Yin J 

PROVIDER: S-EPMC6645584 | biostudies-literature | 2018 Sep

REPOSITORIES: biostudies-literature