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Supramolecular Assembly of a Zn(II)-Based 1D Coordination Polymer through Hydrogen Bonding and ?···? Interactions: Crystal Structure and Device Applications.

ABSTRACT: A new mixed-ligand divalent one-dimensional coordination polymer (1D CP) [Zn(adc)(4-nvp)2(H2O)2] n , (1) [H2adc = acetylenedicarboxylic acid and 4-nvp = 4-(1-naphthylvinyl)pyridine] has been synthesized and well characterized by elemental analysis, infrared spectrum, single-crystal X-ray crystallography, powder X-ray diffraction pattern, and thermogravimetric analysis. The compound 1 constructs a 3D supramolecular network by the combination of hydrogen bonding, C-H···?, and ?···? interactions. Interestingly, the material shows Schottky behavior which is exclusively analyzed with the help of thermionic emission and space charge-limited current theory. In addition, the Schottky barrier diode parameters for compound 1 demonstrate better device performance after light soaking. Hence, the compound has applicability in the fabrication of optoelectronic devices.

SUBMITTER: Dutta B 

PROVIDER: S-EPMC6645665 | biostudies-literature | 2018 Sep

REPOSITORIES: biostudies-literature

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Supramolecular Assembly of a Zn(II)-Based 1D Coordination Polymer through Hydrogen Bonding and π···π Interactions: Crystal Structure and Device Applications.

Dutta Basudeb B   Dey Arka A   Maity Suvendu S   Sinha Chittaranjan C   Ray Partha Pratim PP   Mir Mohammad Hedayetullah MH  

ACS omega 20180927 9

A new mixed-ligand divalent one-dimensional coordination polymer (1D CP) [Zn(adc)(4-nvp)<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>] <sub><i>n</i></sub> , (<b>1</b>) [H<sub>2</sub>adc = acetylenedicarboxylic acid and 4-nvp = 4-(1-naphthylvinyl)pyridine] has been synthesized and well characterized by elemental analysis, infrared spectrum, single-crystal X-ray crystallography, powder X-ray diffraction pattern, and thermogravimetric analysis. The compound <b>1</b> constructs a 3D supramolecular networ  ...[more]

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