Dataset Information

Enhancing Strength of Wool Fiber Using a Soy Flour Sugar-Based "Green" Cross-linker.

ABSTRACT: This study presents the preparation and use of a "green" cross-linker derived from a waste soy flour sugar (SFS) mixture to cross-link keratin in wool fibers to increase their tensile properties. Earlier studies of keratin cross-linking involved chemicals such as glyoxal and glutaraldehyde that are toxic to humans. In addition, their effectiveness in improving tensile properties has been significantly lower than obtained in this study using modified SFS. Characterization of SFS using ¹³C NMR revealed the presence of five sugars having different molecular lengths. Oxidation of SFS using sodium periodate resulted in multiple aldehyde groups, as confirmed by ¹H NMR and attenuated total reflection Fourier-transform infrared (ATR-FTIR). The oxidized SFS (OSFS) when used to cross-link the amine groups from the wool keratin resulted in 36 and 56% increase in the tensile strength and Young's modulus of the fibers, respectively. These significant increases in strength and Young's modulus were a result of having multiple aldehyde groups on each sugar molecule as well as different molecular lengths of sugars, which favored cross-links of multiple lengths within the cortical cell matrix of wool fibers. The cross-linking between the aldehyde groups in OSFS and amine groups in wool fibers was confirmed using ATR-FTIR and from the color change resulting from the Maillard reaction as well as decrease in moisture absorption by the fibers. Stronger wool fibers can not only increase the efficiencies of wool fiber spinning and weaving and reduce yarn and fabric defects but can also allow spinning finer yarns from the same fibers. Oxidized sugars with optimum molecular lengths can be used to cross-link other biological proteins as well, replacing the currently used toxic cross-linkers.

SUBMITTER: Patil NV

PROVIDER: S-EPMC6648322 | biostudies-literature | 2019 Mar

REPOSITORIES: biostudies-literature

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Enhancing Strength of Wool Fiber Using a Soy Flour Sugar-Based "Green" Cross-linker.

Patil Namrata V NV Netravali Anil N AN

ACS omega 20190315 3

This study presents the preparation and use of a "green" cross-linker derived from a waste soy flour sugar (SFS) mixture to cross-link keratin in wool fibers to increase their tensile properties. Earlier studies of keratin cross-linking involved chemicals such as glyoxal and glutaraldehyde that are toxic to humans. In addition, their effectiveness in improving tensile properties has been significantly lower than obtained in this study using modified SFS. Characterization of SFS using <sup>13</su ...[more]

PMID: 31459705

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Project description:The oxidative stability of pretreated full-fat soybean flour (FFSF) was evaluated under commercial (Experiment I) and accelerated conditions (Experiment II). In Experiment I, soybeans were pretreated using germination, soaking (24 h), or roasting (110-120 °C), and the dried, milled FFSF was stored for 120 days under commercial storage conditions in two cities in Ghana. Acid value (AV) and peroxide value (PV) were determined. The proximate and sensory quality of Tuo Zaafi, a maize-only dish in northern Ghana enriched with 10-30% of the pretreated FFSF, was assessed. Before storage, all samples had similar PV (1.907-4.305 mEq/kg oil); however, the AV of the germinated sample was higher than that of the unprocessed samples (10.83 vs. 3.13 mgKOH/g oil; p < 0.001). After storage, although AV fluctuated, the PV was similar (2.39-3.74 mEq/kg oil; p = 1.00). Storage location showed no significant differences in terms of AV (4.96-4.97 mgKOH/g oil; p = 0.994), unlike PV (2.07-3.55 mEq/kg oil; p < 0.001). Increasing the levels of the pretreated FFSF in Tuo Zaafi resulted in lower consumer preference scores for all sensory attributes. In Experiment II, FFSF samples (dehulled and nondehulled) prepared from germination, soaking (18 h and 24 h) and roasting were evaluated under accelerated conditions (AC) of controlled temperature (45 ± 0.1 °C) and relative humidity (81 ± 1%) for AV, PV, p-anisidine value (pAV), lipoxygenase activity (LOX), color, and moisture. Pretreatment, condition, time, and their interaction affected the oxidative stability of all FFSF samples (p < 0.001). Roasted samples showed the highest increase in AV and pAV in both storage conditions (p < 0.05). Under room temperature conditions (RTC), the roasted and germinated samples had lower LOX activity (p < 0.05) at the end of storage time compared to that of the controls. In conclusion, germination and soaking reduced oxidation of FFSF, while roasting promotes it, despite its common use.

Dataset Information

Enhancing Strength of Wool Fiber Using a Soy Flour Sugar-Based "Green" Cross-linker.

Publications

Enhancing Strength of Wool Fiber Using a Soy Flour Sugar-Based "Green" Cross-linker.

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