Dataset Information

Aggregation-Induced Emission-Active Hydrazide-Based Probe: Selective Sensing of Al³⁺, HF₂ ^-, and Nitro Explosives.

ABSTRACT: (E)-N'-((2-Hydroxynaphthalen-1-yl)methylene)picolinohydrazide (H-PNAP) shows aggregation-induced emission (AIE) strictly in a 90% water/MeOH (v/v) mixture at 540 nm, and the solid-state emission is blue-shifted to 509 nm upon excitation at 400 nm. The AIE activity of H-PNAP is selectively quenched by 2,4,6-trinitrophenol (TNP) and 2,4-dinitrophenol (DNP) out of different nitroaromatic compounds with a limit of detection (LOD) of 7.79 × 10^-7 and 9.08 × 10^-7 M, respectively. The probe is nonemissive in aqueous medium (4-(2-hydroxyethyl)-1-piperazineethanesulfonic acid, HEPES buffer, pH 7.2); however, it shows a strong emission to Al³⁺ (?_em, 490 nm) in the presence of 17 other biological metal ions, and the LOD is 2.09 nM which is far below the WHO recommended value (7.41 mM). The emission of the [Al(PNAP)(NO₃)₂] complex is quenched by HF₂ ^- (F^- and PO₄ ^3- are weak quencher), and the LOD is as low as 15 nM. The probable mechanism of the sensing feature of the probe has been authenticated by ¹H nuclear magnetic resonance titration, mass spectrometry, Fourier transform infrared spectroscopy, Benesi-Hildebrand plot, and Job's plot in each case. The probe has some practical applications such as recovery of Al³⁺ from the drinking water sample, construction of the INHIBIT logic gate, and detection kits for Al³⁺ and TNP/DNP by simple paper test strips. The probe, H-PNAP, has successfully been applied to the detection of intracellular Al³⁺ and HF₂ ^- ions in the human breast cancer cell, MDA-MB-468.

SUBMITTER: Dey S

PROVIDER: S-EPMC6648475 | biostudies-literature | 2019 May

REPOSITORIES: biostudies-literature

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Publications

Aggregation-Induced Emission-Active Hydrazide-Based Probe: Selective Sensing of Al3+, HF2 -, and Nitro Explosives.

Dey Sunanda S Purkait Rakesh R Pal Kunal K Jana Kuladip K Sinha Chittaranjan C

ACS omega 20190514 5

(E)-N'-((2-Hydroxynaphthalen-1-yl)methylene)picolinohydrazide (H-PNAP) shows aggregation-induced emission (AIE) strictly in a 90% water/MeOH (v/v) mixture at 540 nm, and the solid-state emission is blue-shifted to 509 nm upon excitation at 400 nm. The AIE activity of H-PNAP is selectively quenched by 2,4,6-trinitrophenol (TNP) and 2,4-dinitrophenol (DNP) out of different nitroaromatic compounds with a limit of detection (LOD) of 7.79 × 10-7 and 9.08 × 10-7 M, ...[more]

PMID: 31459934

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Project description:Coating system(s) will be required for Nb-silicide based alloys. Alumina forming alloys that are chemically compatible with the Nb-silicide based alloy substrate could be components of such systems. The intermetallic alloys Nb1.45Si2.7Ti2.25Al3.25Hf0.35 (MG5) and Nb1.35Si2.3Ti2.3Al3.7Hf0.35 (MG6) were studied in the cast, heat treated and isothermally oxidised conditions at 800 and 1200 °C to find out if they are αAl₂O₃ scale formers. A (Al/Si)alloy versus Nb/(Ti + Hf)alloy map, which can be considered to be a map for Multi-Principle Element or Complex Concentrated Nb-Ti-Si-Al-Hf alloys, and a [Nb/(Ti + Hf)]Nb5Si3 versus [Nb/(Ti + Hf)]alloy map were constructed making use of the alloy design methodology NICE and data from a previously studied alloy, and were used to select the alloys MG5 and MG6 that were expected (i) not to pest, (ii) to form αAl₂O₃ scale at 1200 °C, (iii) to have no solid solution, (iv) to form only hexagonal Nb₅Si₃ and (v) to have microstructures consisting of hexagonal Nb₅Si₃, Ti₅Si₃, Ti₅Si₄, TiSi silicides, and tri-aluminides and Al rich TiAl. Both alloys met the requirements (i) to (v). The alumina scale was able to self-heal at 1200 °C. Liquation in the alloy MG6 at 1200 °C was linked with the formation of a eutectic like structure and the TiAl aluminide in the cast alloy. Key to the oxidation of the alloys was the formation (i) of "composite" silicide grains in which the Nb₅Si₃ core was surrounded by the Ti₅Si₄ and TiSi silicides, and (ii) of tri-aluminides with high Al/Si ratio, particularly at 1200 °C and very low Nb/Ti ratio forming in-between the "composite" silicide grains. Both alloys met the "standard definition" of high entropy alloys (HEAs). Compared with HEAs with bcc solid solution and intermetallics, the VEC values of both the alloys were outside the range of reported values. The parameters VEC,  and  of Nb-Ti-Si-Al-Hf coating alloys and non-pesting Nb-silicide based alloys were compared and trends were established. Selection of coating alloys with possible "layered" structures was discussed and alloy compositions were proposed.

Dataset Information

Aggregation-Induced Emission-Active Hydrazide-Based Probe: Selective Sensing of Al³⁺, HF₂ ^-, and Nitro Explosives.

Publications

Aggregation-Induced Emission-Active Hydrazide-Based Probe: Selective Sensing of Al<sup>3+</sup>, HF<sub>2</sub> <sup>-</sup>, and Nitro Explosives.

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