Dataset Information

Photophysical Properties of an Azine-Linked Pyrene-Cinnamaldehyde Hybrid: Evidence of Solvent-Dependent Charge-Transfer-Coupled Excimer Emission.

ABSTRACT: We report the photophysical properties of a synthetic asymmetric azine-based compound (17Z,18E)-4'-((E)-3-phenylallylidene)-1'-(dimethylamino)-1-((pyren-8-yl)methylene)hydrazine (PYNC). The molecule PYNC shows an appreciable red shift in the emission maximum in a wide range of solvents. In water, PYNC shows the characteristic feature of excimer formation exclusively. However, in all other solvents, the excimer band is present alongside the charge transfer emission band. The assignment of charge transfer and excimer bands has been established by various steady-state emission spectral data. PYNC, owing to this novel excimer-coupled charge transfer phenomenon, can be a potential probe for studying various supramolecular assemblies of biological interest.

SUBMITTER: Bhattacharyya A

PROVIDER: S-EPMC6648816 | biostudies-literature | 2019 Jan

REPOSITORIES: biostudies-literature

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Photophysical Properties of an Azine-Linked Pyrene-Cinnamaldehyde Hybrid: Evidence of Solvent-Dependent Charge-Transfer-Coupled Excimer Emission.

Bhattacharyya Arghyadeep A Makhal Subhash Chandra SC Guchhait Nikhil N

ACS omega 20190129 1

We report the photophysical properties of a synthetic asymmetric azine-based compound (17Z,18E)-4'-((E)-3-phenylallylidene)-1'-(dimethylamino)-1-((pyren-8-yl)methylene)hydrazine (PYNC). The molecule PYNC shows an appreciable red shift in the emission maximum in a wide range of solvents. In water, PYNC shows the characteristic feature of excimer formation exclusively. However, in all other solvents, the excimer band is present alongside the charge transfe ...[more]

PMID: 31459464

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Project description:There is a continuing need to increase the brightness and photostability of fluorophores for use in biotechnology, medical diagnostics, and cell imaging. One approach developed during the past decade is to use metallic surfaces and nanostructures. It is now known that excited state fluorophores display interactions with surface plasmons, which can increase the radiative decay rates, modify the spatial distribution of emission, and result in directional emission. One important example is surface plasmon-coupled emission (SPCE). In this phenomenon, the fluorophores at close distances from a thin metal film, typically silver, display emission over a small range of angles into the substrate. A disadvantage of SPCE is that the emission occurs at large angles relative to the surface normal and at angles that are larger than the critical angle for the glass substrate. The large angles make it difficult to collect all of the coupled emission and have prevented the use of SPCE with high-throughput and/or array applications. In the current article, we describe a simple multilayer metal-dielectric structure that allows excitation with light that is perpendicular (normal) to the plane and provides emission within a narrow angular distribution that is normal to the plane. This structure consists of a thin silver film on top of a multilayer dielectric Bragg grating, with no nanoscale features except for the metal or dielectric layer thicknesses. Our structure is designed to support optical Tamm states, which are trapped electromagnetic modes between the metal film and the underlying Bragg grating. We used simulations with the transfer matrix method to understand the optical properties of Tamm states and localization of the modes or electric fields in the structure. Tamm states can exist with zero in-plane wavevector components and can be created without the use of a coupling prism. We show that fluorophores on top of the metal film can interact with the Tamm state under the metal film and display Tamm state-coupled emission (TSCE). In contrast to SPCE, the Tamm states can display either S or P polarization. The TSCE angle is highly sensitive to wavelength, which suggests the use of Tamm structures to provide both directional emission and wavelength dispersion. Metallic structures can modify fluorophore decay rates but also have high losses. Photonic crystals have low losses but may lack the enhanced light-induced fields near metals. The combination of plasmonic and photonic structures offers the opportunity for radiative decay engineering to design new formats for clinical testing and other fluorescence-based applications.

Dataset Information

Photophysical Properties of an Azine-Linked Pyrene-Cinnamaldehyde Hybrid: Evidence of Solvent-Dependent Charge-Transfer-Coupled Excimer Emission.

Publications

Photophysical Properties of an Azine-Linked Pyrene-Cinnamaldehyde Hybrid: Evidence of Solvent-Dependent Charge-Transfer-Coupled Excimer Emission.

Similar Datasets

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