Ontology highlight
ABSTRACT:
SUBMITTER: Gautam P
PROVIDER: S-EPMC6648871 | biostudies-literature | 2019 Jan
REPOSITORIES: biostudies-literature
Gautam Prashant P Tiwari Neelam J NJ Bhanage Bhalchandra M BM
ACS omega 20190117 1
This work documents the first palladium pincer complex-catalyzed carbonylative Sonogashira (CS) and carbonylative Suzuki-Miyaura (CSM) cross-coupling. Compared to previous protocols, which employ hazardous and toxic solvents, the aminophosphine pincer complex {[C<sub>6</sub>H<sub>3</sub>-2,6-(NHP{piperidinyl}<sub>2</sub>)<sub>2</sub>]Pd(Cl)} (<b>III</b>) catalyzes both the cross-coupling reactions in propylene carbonate, an eco-friendly and sustainable polar aprotic solvent. Advantageously, empl ...[more]