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Oxidizing and Nano-dispersing the Natural Silk Fibers.

ABSTRACT: Natural Bombyx mori silk (BS) and Antheraea pernyi silk (AS) were oxidized in sodium hypochlorite (NaClO) solutions. Thereafter, individual silk nanofibers (SNs) were achieved after sonicating the oxidized silk slurries, where the diameters of the resultant SNs were ~?100?nm and several micrometers in length. Thin membranes were formed by casting the SNs, which had optically transparent (above 75% transmission), mechanically robust (~4.5?GPa of Young's modulus), and enhanced wetting properties. An interesting aggregating-dispersing (re-dispersing) process by using these SNs was strongly regulated by adjusting the pH values. Consequently, the negatively charged SNs could be concentrated up to ~?20?wt% (100 times that of the initial dispersion) and offered extraordinary benefits for storage, transportation, and engineering applications.

SUBMITTER: Zheng K

PROVIDER: S-EPMC6658644 | biostudies-literature | 2019 Jul

REPOSITORIES: biostudies-literature

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Oxidizing and Nano-dispersing the Natural Silk Fibers.

Zheng Ke K Hu Yanlei Y Zhang Wenwen W Yu Juan J Ling Shengjie S Fan Yimin Y

Nanoscale research letters 20190725 1

Natural Bombyx mori silk (BS) and Antheraea pernyi silk (AS) were oxidized in sodium hypochlorite (NaClO) solutions. Thereafter, individual silk nanofibers (SNs) were achieved after sonicating the oxidized silk slurries, where the diameters of the resultant SNs were ~ 100 nm and several micrometers in length. Thin membranes were formed by casting the SNs, which had optically transparent (above 75% transmission), mechanically robust (~4.5 GPa of Young's modulus), and enhanced wetting properties. ...[more]

PMID: 31346786

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