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Hirshfeld surface analysis and crystal structure of N-(2-meth-oxy-phen-yl)acetamide.

ABSTRACT: The title compound, C₉H₁₁NO₂, was obtained as unexpected product from the reaction of (4-{2-benz-yloxy-5-[(E)-(3-chloro-4-methyl-phen-yl)diazen-yl]benzyl-idene}-2-phenyl-oxazol-5(4H)-one) with 2-meth-oxy-aniline in the presence of acetic acid as solvent. The amide group is not coplanar with the benzene ring, as shown by the C-N-C-O and C-N-C-C torsion angles of -2.5 (3) and 176.54 (19)°, respectively. Hirshfeld surface analysis and two-dimensional fingerprint plots indicate that the most important contributions to the crystal packing are from H⋯H (53.9%), C⋯H/H⋯C (21.4%), O⋯H/H⋯O (21.4%) and N⋯H/H⋯N (1.7%) inter-actions.

SUBMITTER: Yaman M

PROVIDER: S-EPMC6658953 | biostudies-literature | 2019 Jun

REPOSITORIES: biostudies-literature

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Hirshfeld surface analysis and crystal structure of N-(2-meth-oxy-phen-yl)acetamide.

Yaman Mavise M Dege Necmi N Ayoob Mzgin M MM Hussein Awaz J AJ Samad Mohammed K MK Fritsky Igor O IO

Acta crystallographica. Section E, Crystallographic communications 20190521 Pt 6

The title compound, C9H11NO2, was obtained as unexpected product from the reaction of (4-{2-benz-yloxy-5-[(E)-(3-chloro-4-methyl-phen-yl)diazen-yl]benzyl-idene}-2-phenyl-oxazol-5(4H)-one) with 2-meth-oxy-aniline in the presence of acetic acid as solvent. The amide group is not coplanar with the benzene ring, as shown by the C-N-C-O and C-N-C-C torsion angles of -2.5 (3) and 176.54 (19)°, respectively. Hirshfeld surface analysis and two-dimensional f ...[more]

PMID: 31391976

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