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Crystal structure of N-(di-phenyl-phosphor-yl)-2-meth-oxy-benzamide.

ABSTRACT: In the title compound, C₂₀H₁₈NO₃P, the C=O and P=O groups of the carbacyl-amido-phosphate (CAPh) fragments are located in a synclinal position relative to each other and are pre-organized for bidentate chelate coordination of metal ions. The N-H group is involved in the formation of an intra-molecular hydrogen bond. In the crystal, mol-ecules do not form strong inter-molecular inter-actions but the mol-ecules are linked via weak C-H?? inter-actions, forming chains along [001].

SUBMITTER: Trush VA

PROVIDER: S-EPMC6659338 | biostudies-literature | 2019 Jul

REPOSITORIES: biostudies-literature

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Crystal structure of N-(di-phenyl-phosphor-yl)-2-meth-oxy-benzamide.

Trush Victor A VA Kariaka Nataliia S NS Dyakonenko Viktoriya V VV Shishkina Svitlana V SV Amirkhanov Vladimir M VM

Acta crystallographica. Section E, Crystallographic communications 20190604 Pt 7

In the title compound, C20H18NO3P, the C=O and P=O groups of the carbacyl-amido-phosphate (CAPh) fragments are located in a synclinal position relative to each other and are pre-organized for bidentate chelate coordination of metal ions. The N-H group is involved in the formation of an intra-molecular hydrogen bond. In the crystal, mol-ecules do not form strong inter-molecular inter-actions but the mol-ecules are linked via weak C-H⋯π inter-actions, formin ...[more]

PMID: 31391999

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