Facile Fabrication of Au Nanoparticles/Tin Oxide/Reduced Graphene Oxide Ternary Nanocomposite and Its High-Performance SF₆ Decomposition Components Sensing.

ABSTRACT: A high-performance sensor for detecting SF₆ decomposition components (H₂S and SOF₂) was fabricated via hydrothermal method using Au nanoparticles/tin oxide/reduced graphene oxide (AuNPs-SnO₂-reduced graphene oxide [rGO]) hybrid nanomaterials. The sensor has gas-sensing properties that responded and recovered rapidly at a relatively low operating temperature. The structure and micromorphology of the prepared materials were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), Raman spectroscopy, energy-dispersive spectroscopy (EDS), and Brunauer-Emmett-Teller (BET). The gas-sensing properties of AuNPs-SnO₂-rGO hybrid materials were studied by exposure to target gases. Results showed that AuNPs-SnO₂-rGO sensors had desirable response/recovery time. Compared with pure rGO (210/452 s, 396/748 s) and SnO₂/rGO (308/448 s, 302/467 s), the response/recovery time ratios of AuNPs-SnO₂-rGO sensors for 50 ppm H₂S and 50 ppm SOF₂ at 110°C were 26/35 s and 41/68 s, respectively. Furthermore, the two direction-resistance changes of the AuNPs-SnO₂-rGO sensor when exposed to H₂S and SOF₂ gas made this sensor a suitable candidate for selective detection of SF₆ decomposition components. The enhanced sensing performance can be attributed to the heterojunctions with the highly conductive graphene, SnO₂ films and Au nanoparticles.

SUBMITTER: Pi S 

PROVIDER: S-EPMC6660266 | biostudies-literature | 2019

REPOSITORIES: biostudies-literature