Realizing nearly-free-electron like conduction band in a molecular film through mediating intermolecular van der Waals interactions.

ABSTRACT: Collective molecular physical properties can be enhanced from their intrinsic characteristics by templating at material interfaces. Here we report how a black phosphorous (BP) substrate concatenates a nearly-free-electron (NFE) like conduction band of a C₆₀ monolayer. Scanning tunneling microscopy reveals the C₆₀ lowest unoccupied molecular orbital (LUMO) band is strongly delocalized in two-dimensions, which is unprecedented for a molecular semiconductor. Experiment and theory show van der Waals forces between C₆₀ and BP reduce the inter-C₆₀ distance and cause mutual orientation, thereby optimizing the ?-? wave function overlap and forming the NFE-like band. Electronic structure and carrier mobility calculations predict that the NFE band of C₆₀ acquires an effective mass of 0.53-0.70 m_e (m_e is the mass of free electrons), and has carrier mobility of ~200 to 440 cm²V^-1s^-1. The substrate-mediated intermolecular van der Waals interactions provide a route to enhance charge delocalization in fullerenes and other organic semiconductors.

SUBMITTER: Cui X 

PROVIDER: S-EPMC6662711 | biostudies-literature | 2019 Jul

REPOSITORIES: biostudies-literature