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Melt-Mixed Thermoplastic Nanocomposite Containing Carbon Nanotubes and Titanium Dioxide for Flame Retardancy Applications.

ABSTRACT: The study of polymeric nanocomposites is a possible alternative to conventional flame retardants. The aim of the present work is to investigate the effects of carbon-nanotubes (CNT) and TiO₂ nanoparticles (NPs) on the thermo-mechanical, flammability, and electrical properties of polypropylene (PP). In this work, PP-TiO₂/CNT nanocomposites were obtained with TiO₂/CNT mixtures (ratio 1:2) through the melt extrusion process, with different weight percentage of nanoparticles (1, 5, and 10 wt %). The PP-TiO₂/CNT nanocomposites were characterized by DSC, TGA, MFI, FTIR, XRD, and SEM. It was possible to determine that the thermal stability of the PP increases when increasing the content of NPs. A contrary situation is observed in the degree of crystallinity and thermo-oxidative degradation, which decreased with respect to pure PP. The TiO₂ NPs undergo coalition and increase their size at a lower viscosity of the nanocomposite (1 and 5 wt %). The mechanical properties decreased slightly, however, the Young's modulus presented an improvement of 10% as well as electrical conductivity, this behavior was noted in nanocomposites of 10 wt % of NPs. Flammability properties were measured with a cone calorimeter, and a reduction in the peak heat release rate was observed in nanocomposites with contents of nanoparticles of 5 and 10 wt.

SUBMITTER: Cabello-Alvarado C

PROVIDER: S-EPMC6680381 | biostudies-literature | 2019 Jul

REPOSITORIES: biostudies-literature

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Melt-Mixed Thermoplastic Nanocomposite Containing Carbon Nanotubes and Titanium Dioxide for Flame Retardancy Applications.

Cabello-Alvarado C C Reyes-Rodríguez P P Andrade-Guel M M Cadenas-Pliego G G Pérez-Alvarez M M Cruz-Delgado V J VJ Melo-López L L Quiñones-Jurado Z V ZV Ávila-Orta C A CA

Polymers 20190719 7

The study of polymeric nanocomposites is a possible alternative to conventional flame retardants. The aim of the present work is to investigate the effects of carbon-nanotubes (CNT) and TiO2 nanoparticles (NPs) on the thermo-mechanical, flammability, and electrical properties of polypropylene (PP). In this work, PP-TiO2/CNT nanocomposites were obtained with TiO2/CNT mixtures (ratio 1:2) through the melt extrusion process, with different weight percentage of nanop ...[more]

PMID: 31330943

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Project description:The effects of combining 0.1-5 wt % graphene nanoplatelet (GNP) and 3-30 wt % phosphorous flame retardant, 9,10- dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO) as fillers in epoxy polymer on the mechanical, flame retardancy, and electrical properties of the epoxy nanocomposites was investigated. GNP was homogeneously dispersed into the epoxy matrix using a solvent-free three-roll milling process, while DOPO was incorporated into the epoxy resin by mechanical stirring at elevated temperature. The incorporation of DOPO reduced the crosslinking density of the epoxy resin. When using polyetheramine as a hardener, the structural rigidity effect of DOPO overshadowed the crosslinking effect and governed the flexural moduli of epoxy/DOPO resins. The flexural moduli of the nanocomposites were improved by adding GNP up to 5 wt % and DOPO up to 30 wt %, whereas the flexural strengths deteriorated when the GNP and DOPO loading were higher than 1 wt % and 10 wt %, respectively. Limited by the adverse effects on mechanical property, the loading combinations of GNP and DOPO within the range of 0-1 wt % and 0-10 wt %, respectively, in epoxy resin were further studied. Flame retardancy index (FRI), which depended on three parameters obtained from cone calorimetry, was considered to evaluate the flame retardancy of the epoxy composites. DOPO showed better performance than GNP as the flame retardant additive, while combining DOPO and GNP could further improve FRI to some extent. With the combination of 0.5 wt % GNP and 10 wt % DOPO, improvement in both mechanical properties and flame retardant efficiency of the nanocomposite was observed. Such a combination did not affect the electrical conductivity of the nanocomposites since the percolation threshold was at 1.6 wt % GNP. Our results enhance the understanding of the structure-property relationship of additive-filled epoxy resin composites and serve as a property constraining guidance for the composite manufacturing.

Dataset Information

Melt-Mixed Thermoplastic Nanocomposite Containing Carbon Nanotubes and Titanium Dioxide for Flame Retardancy Applications.

Publications

Melt-Mixed Thermoplastic Nanocomposite Containing Carbon Nanotubes and Titanium Dioxide for Flame Retardancy Applications.

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