CoNi₂S₄ Nanoplate Arrays Derived from Hydroxide Precursors for Flexible Fiber-Shaped Supercapacitors.

ABSTRACT: A high-quality porous CoNi₂S₄ nanoplates array was in situ synthesized on carbon fibers (CFs) by a hydrothermal method via a CoNi-layered double hydroxide (LDH) precursor transformation process. The CoNi₂S₄@CFs electrode exhibits largely enhanced supercapacitor performance with a specific capacitance of 1724 F/g at 1 A/g, in comparison with that of the CoNi-LDH (1302 F/g) precursor. Furthermore, the CoNi₂S₄@CF electrode shows an extremely high rate capability with capacity retention of 79% under a charge density of 60 A/g, whereas the retention rate of CoNi-LDH@CFs is only ?34%. The abundant pore structure, improved electrical conductivity, and lower internal resistances of CoNi₂S₄@CFs (1.0 ?) compared to those of CoNi-LDH@CFs (9.5 ?) are responsible for the enhancement of energy storage performance. By using the CoNi₂S₄ nanoplate array as the positive electrode, an all-solid-state asymmetric fiber-shaped supercapacitor was further obtained, which exhibits outstanding flexible, foldable, and wearable capability. In view of the component tunability for LDH materials, the hydroxide precursor transformation method with merits of mild conditions and easy operation can be extended to the synthesis of a variety of metal sulfides for broad applications in electronic devices.

SUBMITTER: Zhang J 

PROVIDER: S-EPMC6682062 | biostudies-literature | 2019 Jul

REPOSITORIES: biostudies-literature