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Miscibility Tuning for Optimizing Phase Separation and Vertical Distribution toward Highly Efficient Organic Solar Cells.

ABSTRACT: Blending multidonor or multiacceptor organic materials as ternary devices has been recognized as an efficient and potential method to improve the power conversion efficiency of bulk heterojunction devices or single-junction components in tandem design. In this work, a highly crystalline molecule, DRCN5T, is involved into a PTB7-Th:PC₇₀BM system to fabricate large-area organic solar cells (OSCs) whose blend film thickness is up to 270 nm, achieving an impressive performance of 11.1%. The significant improvement of OSCs after adding DRCN5T is due to the formation of an interconnected fibrous network with decreased ?-? stacking and enhanced domain purity, in addition to the optimized vertical distribution of PTB7-Th and PC₇₀BM, producing more effective charge separation, transport, and collection. The optimized morphology and performance are actually determined by the miscibility in different components, which can be quantitatively described by the Flory-Huggins interaction parameter of -0.80 and 2.94 in DRCN5T:PTB7-Th and DRCN5T:PC₇₀BM blends, respectively. The findings in this work can potentially guide the selection of an appropriate third additive for high-performance OSCs for the sake of large-area printing and roll-to-roll fabrication from the view of miscibility.

SUBMITTER: Zhang L

PROVIDER: S-EPMC6685468 | biostudies-literature | 2019 Aug

REPOSITORIES: biostudies-literature

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Miscibility Tuning for Optimizing Phase Separation and Vertical Distribution toward Highly Efficient Organic Solar Cells.

Zhang Lifu L Yi Nan N Zhou Weihua W Yu Zoukangning Z Liu Feng F Chen Yiwang Y

Advanced science (Weinheim, Baden-Wurttemberg, Germany) 20190522 15

Blending multidonor or multiacceptor organic materials as ternary devices has been recognized as an efficient and potential method to improve the power conversion efficiency of bulk heterojunction devices or single-junction components in tandem design. In this work, a highly crystalline molecule, DRCN5T, is involved into a PTB7-Th:PC<sub>70</sub>BM system to fabricate large-area organic solar cells (OSCs) whose blend film thickness is up to 270 nm, achieving an impressive performance of 11.1%. T ...[more]

PMID: 31406670

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Project description:Metal-organic framework nanosheets (MONs) have proved themselves to be useful additives for enhancing the performance of a variety of thin film solar cell devices. However, to date only isolated examples have been reported. In this work we take advantage of the modular structure of MONs in order to resolve the effect of their different structural and optoelectronic features on the performance of organic photovoltaic (OPV) devices. Three different MONs were synthesized using different combinations of two porphyrin-based ligands meso-tetracarboxyphenyl porphyrin (TCPP) or tetrapyridyl-porphyrin (TPyP) with either zinc and/or copper ions and the effect of their addition to polythiophene-fullerene (P3HT-PC71BM) OPV devices was investigated. The power conversion efficiency (PCE) of devices was found to approximately double with the addition of MONs of Zn2(ZnTCPP) -4.7% PCE, 10.45 mA/cm2 short-circuit current density (JSC), 0.69 open-circuit voltage (VOC), 64.20% fill-factor (FF), but was unchanged with the addition of Cu2(ZnTPyP) (2.6% PCE, 3.68 mA/cm2 JSC, 0.59 VOC, 46.27% FF) and halved upon the addition of Cu2(CuTCPP) (1.24% PCE, 6.72 mA/cm2 JSC, 0.59 VOC, 56.24% FF) compared to devices without nanosheets (2.6% PCE, 6.61 mA/cm2 JSC, 0.58 VOC, 56.64% FF). Our analysis indicates that there are three different mechanisms by which MONs can influence the photoactive layer - light absorption, energy level alignment, and morphological changes. Analysis of external quantum efficiency, UV-vis and photoelectron spectroscopy data found that MONs have similar effects on light absorption and energy level alignment. However, atomic force and Raman microscopy studies revealed that the nanosheet thickness and lateral size are crucial parameters in enabling the MONs to act as beneficial additives resulting in an improvement of the OPV device performance. We anticipate this study will aid in the design of MONs and other 2D materials for future use in other light harvesting and emitting devices.

Dataset Information

Miscibility Tuning for Optimizing Phase Separation and Vertical Distribution toward Highly Efficient Organic Solar Cells.

Publications

Miscibility Tuning for Optimizing Phase Separation and Vertical Distribution toward Highly Efficient Organic Solar Cells.

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