Miscibility Tuning for Optimizing Phase Separation and Vertical Distribution toward Highly Efficient Organic Solar Cells.

ABSTRACT: Blending multidonor or multiacceptor organic materials as ternary devices has been recognized as an efficient and potential method to improve the power conversion efficiency of bulk heterojunction devices or single-junction components in tandem design. In this work, a highly crystalline molecule, DRCN5T, is involved into a PTB7-Th:PC₇₀BM system to fabricate large-area organic solar cells (OSCs) whose blend film thickness is up to 270 nm, achieving an impressive performance of 11.1%. The significant improvement of OSCs after adding DRCN5T is due to the formation of an interconnected fibrous network with decreased ?-? stacking and enhanced domain purity, in addition to the optimized vertical distribution of PTB7-Th and PC₇₀BM, producing more effective charge separation, transport, and collection. The optimized morphology and performance are actually determined by the miscibility in different components, which can be quantitatively described by the Flory-Huggins interaction parameter of -0.80 and 2.94 in DRCN5T:PTB7-Th and DRCN5T:PC₇₀BM blends, respectively. The findings in this work can potentially guide the selection of an appropriate third additive for high-performance OSCs for the sake of large-area printing and roll-to-roll fabrication from the view of miscibility.

SUBMITTER: Zhang L 

PROVIDER: S-EPMC6685468 | biostudies-literature | 2019 Aug

REPOSITORIES: biostudies-literature