Browse
Submit Data
Databases
API
Help

Dataset Information

8 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

An Efficient Electrochemical Sensor Driven by Hierarchical Hetero-Nanostructures Consisting of RuO2 Nanorods on WO3 Nanofibers for Detecting Biologically Relevant Molecules.

ABSTRACT: By means of electrospinning with the thermal annealing process, we investigate a highly efficient sensing platform driven by a hierarchical hetero-nanostructure for the sensitive detection of biologically relevant molecules, consisting of single crystalline ruthenium dioxide nanorods (RuO2 NRs) directly grown on the surface of electrospun tungsten trioxide nanofibers (WO3 NFs). Electrochemical measurements reveal the enhanced electron transfer kinetics at the prepared RuO2 NRs-WO3 NFs hetero-nanostructures due to the incorporation of conductive RuO2 NRs nanostructures with a high surface area, resulting in improved relevant electrochemical sensing performances for detecting H2O2 and L-ascorbic acid with high sensitivity.

SUBMITTER: Lee H

PROVIDER: S-EPMC6696473 | biostudies-literature | 2019 Jul

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

An Efficient Electrochemical Sensor Driven by Hierarchical Hetero-Nanostructures Consisting of RuO2 Nanorods on WO3 Nanofibers for Detecting Biologically Relevant Molecules.

Lee Hyerim H Kim Yeomin Y Yu Areum A Jin Dasol D Jo Ara A Lee Youngmi Y Kim Myung Hwa MH Lee Chongmok C

Sensors (Basel, Switzerland) 20190726 15

By means of electrospinning with the thermal annealing process, we investigate a highly efficient sensing platform driven by a hierarchical hetero-nanostructure for the sensitive detection of biologically relevant molecules, consisting of single crystalline ruthenium dioxide nanorods (RuO2 NRs) directly grown on the surface of electrospun tungsten trioxide nanofibers (WO3 NFs). Electrochemical measurements reveal the enhanced electron transfer kinetics at the prepared RuO<s ...[more]

PMID: 31357512

Similar Datasets

Hollow WO3/SnO2 Hetero-Nanofibers: Controlled Synthesis and High Efficiency of Acetone Vapor Detection.

Project description:Metal oxide hetero-nanostructures have widely been used as the core part of chemical gas sensors. To improve the dispersion state of each constituent and the poor stability that exists in heterogeneous gas sensing materials, a uniaxial electro-spinning method combined with calcination was applied to synthesize pure SnO2 and three groups of WO3/SnO2 (WO3 of 0.1, 0.3, 0.9 wt%) hetero-nanofibers (HNFs) in our work. A series of characterizations prove that the products present hollow and fibrous structures composed of even nanoparticles while WO3 is uniformly distributed into the SnO2 matrix. Gas sensing tests display that the WO3/SnO2 (0.3 wt%) sensor not only exhibits the highest response (30.28) and excellent selectivity to acetone vapor at the lower detection temperature (170°C), 6 times higher than that of pure SnO2 (5.2), but still achieves a considerable response (4.7) when the acetone concentration is down to 100 ppb with the corresponding response/recovery times of 50/200 s, respectively. Such structure obviously enhances the gas sensing performance toward acetone which guides the construction of a highly sensitive acetone sensor. Meanwhile, the enhancement mechanism of such a special sensor is also discussed in detail.

| S-EPMC6884032 | biostudies-literature

A self-assembled photoresponsive gel consisting of chiral nanofibers.

Project description:A novel compound based on a glutamic acid skeleton, containing azobenzene as a photoresponsive group and ureidopyrimidinone (UPy) as a connection site, was designed and synthesized. The monomer is capable of forming an organogel in nonpolar organic solvents and different types of nanostructures in other solvents. The state of the gel and the chirality of the nanostructures could both be adjusted by subsequent light irradiation at different wavelengths. The helical nanofiber-like morphology was verified in the internal structure of the gel. The performance of this gel was investigated by a series of methods, such as UV-vis absorption spectroscopy, circular dichroism, scanning electron microscopy and rheological techniques. This work provides a new method for facile synthesis of chiro-optical gels.

| S-EPMC6122117 | biostudies-literature

Arbitrary multicolor photodetection by hetero-integrated semiconductor nanostructures.

Project description:The typical photodetectors can only detect one specific optical spectral band, such as InGaAs and graphene-PbS quantum dots for near-infrared (NIR) light detection, CdS and Si for visible light detection, and ZnO and III-nitrides for UV light detection. So far, none of the developed photodetector can achieve the multicolor detection with arbitrary spectral selectivity, high sensitivity, high speed, high signal-to-noise ratio, high stability, and simplicity (called 6S requirements). Here, we propose a universal strategy to develop multicolor photodetectors with arbitrary spectral selectivity by integrating various semiconductor nanostructures on a wide-bandgap semiconductor or an insulator substrate. Because the photoresponse of each spectral band is determined by each semiconductor nanostructure or the semiconductor substrate, multicolor detection satisfying 6S requirements can be readily satisfied by selecting the right semiconductors.

| S-EPMC3734442 | biostudies-literature

Color tuning of nanofibers by periodic organic-organic hetero-epitaxy.

Project description:We report on the epitaxial growth of periodic para-hexaphenyl (p-6P)/?-sexi-thiophene (6T) multilayer heterostructures on top of p-6P nanotemplates. By the chosen approach, 6T molecules are forced to align parallel to the p-6P template molecules, which yields highly polarized photoluminescence (PL)-emission of both species. The PL spectra show that the fabricated multilayer structures provide optical emission from two different 6T phases, interfacial 6T molecules, and 3-dimensional crystallites. By a periodical deposition of 6T monolayers and p-6P spacers it is demonstrated that the strongly polarized spectral contribution of interfacial 6T can be precisely controlled and amplified. By analyzing the PL emission of both 6T phases as a function of p-6P spacer thickness (?d(p-6P)) we have determined a critical value of ?d(p-6P )? 2.73 nm where interfacial 6T runs into saturation and the surplus of 6T starts to cluster in 3-dimensional crystallites. These results are further substantiated by UPS and XRD measurements. Moreover, it is demonstrated by morphological investigations, provided by scanning force microscopy and fluorescence microscopy, that periodical deposition of 6T and p-6P leads to a significant improvement of homogeneity in PL-emission and morphology of nanofibers. Photoluminescence excitation experiments in combination with time-resolved photoluminescence demonstrate that the spectral emission of the organic multilayer nanofibers is dominated by a resonant energy transfer from p-6P host- to 6T guest-molecules. The sensitization time of the 6T emission in the 6T/p-6P multilayer structures depends on the p-6P spacer thickness, and can be explained by well separated layers of host-guest molecules obtained by organic-organic heteroepitaxy. The spectral emission and consequently the fluorescent color of the nanofibers can be efficiently tuned from the blue via white to the yellow-green spectral range.

| S-EPMC3395255 | biostudies-literature

Hierarchical Self-Assembly of Cholesterol-DNA Nanorods.

Project description:Amphiphilic DNA block copolymers have been utilized in preparing self-assembled amphiphilic structures in aqueous solution. These block copolymers usually contain specifically designed hydrophobic regions, and typically assemble under near-physiological conditions. Here, we report self-assembly of spherical micelles and one-dimensional nanorods under acidic conditions from cholesterol-conjugated DNA strands (Cholesterol-DNA). Further study also revealed that the nanorods were hierarchically assembled from the micelle nanostructures. The morphology of the nanorod assemblies can be tuned by altering solution condition and the design of Cholesterol-DNA. The self-assembly of Cholesterol-DNA nanostructures under acidic conditions and the discovery of the relationship between the nanorods and the micelles can provide new insights for future design of self-assemblies of amphiphilic DNA block copolymers.

| S-EPMC7254875 | biostudies-literature

Anisotropic dual-plasmonic hetero-nanostructures with tunable plasmonic coupling effects.

Project description:The influence of plasmonic coupling effects between different components in Au NRs@Cu2-x Se nanostructures on their characteristics was studied. To this aim, anisotropic Au@Cu2-x Se hetero-nanostructures with well-controlled design and optical properties were obtained. The LSPR bands of gold and copper selenide are superpositioned in the NIR region, resulting in superior photocatalytic properties of the nanostructures.

| S-EPMC9419501 | biostudies-literature

Synthesis of biologically derived poly(pyrogallol) nanofibers for antibacterial applications.

Project description:Herein, we present the facile synthesis of poly(pyrogallol) biopolymers and their application as antibacterial agents. Pyrogallol is a class of phenolic compounds that can be found in various plants. Polymerization was performed by the auto-oxidation of pyrogallol under a hydrated condition. The microscopic image of poly(pyrogallol) shows a highly homogenous nanofibrous structure with a diameter of 100.3 ± 16.3 nm. Spectroscopic analysis by FT-IR spectroscopy, Raman spectroscopy, and XPS corroborated the formation of ether (C-O-C) bonds between the hydroxyl group and adjacent carbons of pyrogallol during polymerization. The FT-IR and XPS spectra also revealed redox-active gallol functional groups on poly(pyrogallol) nanofibers, which can be used to release free electrons and protons during oxidation followed by the generation of reactive oxygen species (ROS). The generated ROS from poly(pyrogallol) was used to inhibit the growth of bacteria, Escherichia coli, at a inhibition rates of 56.3 ± 9.7% and 95.5 ± 2.0% within 0.5 and 2 h, respectively. This finding suggests that poly(pyrogallol) can be used as a naturally occurring antibacterial agent for various biomedical and environmental applications.

| S-EPMC10387265 | biostudies-literature

A broadband achromatic polarization-insensitive metalens consisting of anisotropic nanostructures.

Project description:Metasurfaces have attracted widespread attention due to an increasing demand of compact and wearable optical devices. For many applications, polarization-insensitive metasurfaces are highly desirable, and appear to limit the choice of their constituent elements to isotropic nanostructures. This greatly restricts the number of geometric parameters available in design. Here, we demonstrate a polarization-insensitive metalens using otherwise anisotropic nanofins which offer additional control over the dispersion and phase of the output light. As a result, we can render a metalens achromatic and polarization-insensitive across nearly the entire visible spectrum from wavelength ??=?460?nm to 700?nm, while maintaining diffraction-limited performance. The metalens is comprised of just a single layer of TiO2 nanofins and has a numerical aperture of 0.2 with a diameter of 26.4?µm. The generality of our polarization-insensitive design allows it to be implemented in a plethora of other metasurface devices with applications ranging from imaging to virtual/augmented reality.

| S-EPMC6341080 | biostudies-other

Biologically inspired LED lens from cuticular nanostructures of firefly lantern.

Project description:Cuticular nanostructures found in insects effectively manage light for light polarization, structural color, or optical index matching within an ultrathin natural scale. These nanostructures are mainly dedicated to manage incoming light and recently inspired many imaging and display applications. A bioluminescent organ, such as a firefly lantern, helps to out-couple light from the body in a highly efficient fashion for delivering strong optical signals in sexual communication. However, the cuticular nanostructures, except the light-producing reactions, have not been well investigated for physical principles and engineering biomimetics. Here we report a unique observation of high-transmission nanostructures on a firefly lantern and its biological inspiration for highly efficient LED illumination. Both numerical and experimental results clearly reveal high transmission through the nanostructures inspired from the lantern cuticle. The nanostructures on an LED lens surface were fabricated by using a large-area nanotemplating and reconfigurable nanomolding with heat-induced shear thinning. The biologically inspired LED lens, distinct from a smooth surface lens, substantially increases light transmission over visible ranges, comparable to conventional antireflection coating. This biological inspiration can offer new opportunities for increasing the light extraction efficiency of high-power LED packages.

| S-EPMC3503230 | biostudies-literature

Synthesis of TiO2/WO3 Composite Nanofibers by a Water-Based Electrospinning Process and Their Application in Photocatalysis.

Project description:TiO2/WO3 nanofibers were prepared in a one-step process by electrospinning. Titanium(IV) bis(ammonium lactato)dihydroxide (TiBALDH) and ammonium metatungstate (AMT) were used as water-soluble Ti and W precursors, respectively. Polyvinylpyrrolidone (PVP) and varying ratios of TiBALDH and AMT were dissolved in a mixture of H2O, EtOH and CH3COOH. The as-spun fibers were then heated in air at 1 °C min-1 until 600 °C to form TiO2/WO3 composite nanofibers. Fiber characterization was done using TG/DTA, SEM-EDX, FTIR, XRD, and Raman. The annealed composite nanofibers had a diameter range of 130-1940 nm, and the results showed a growth in the fiber diameter with an increasing amount of WO3. The photocatalytic property of the fibers was also checked for methyl orange bleaching in visible and UV light. In visible light, the photocatalytic activity increased with an increase in the ratio of AMT, while 50% TiBALDH composite fibers showed the highest activity among the as-prepared fibers in UV light.

| S-EPMC7279266 | biostudies-literature