Unknown

Dataset Information

0

Reversible Thermochromism of Nickel(II) Complexes and Single-Crystal-to-Single-Crystal Transformation.

ABSTRACT: A molecular Ni(II)-NNN pincer complex (1) exhibited unprecedented reversible single-crystal-to-single-crystal transformation and color change upon heating and cooling due to a subtle change in the N-Ni(II) bond length and ligand conformation. UV-vis, thermogravimetric, differential scanning calorimetry, single-crystal structural data, temperature-dependent powder X-ray diffraction, and Raman and computational studies supported the structural change of the Ni(II) complex with temperature.

SUBMITTER: Pitchaimani J 

PROVIDER: S-EPMC6714294 | biostudies-literature | 2019 Aug

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Reversible Thermochromism of Nickel(II) Complexes and Single-Crystal-to-Single-Crystal Transformation.

Pitchaimani Jayaraman J   Karthikeyan Subramanian S   Lakshminarasimhan Narayanan N   Anthony Savarimuthu Philip SP   Moon Dohyun D   Madhu Vedichi V  

ACS omega 20190815 9

A molecular Ni(II)-NNN pincer complex (<b>1</b>) exhibited unprecedented reversible single-crystal-to-single-crystal transformation and color change upon heating and cooling due to a subtle change in the N-Ni(II) bond length and ligand conformation. UV-vis, thermogravimetric, differential scanning calorimetry, single-crystal structural data, temperature-dependent powder X-ray diffraction, and Raman and computational studies supported the structural change of the Ni(II) complex with temperature. ...[more]

Similar Datasets

Unknown Reversible single-crystal to single-crystal phase transformation between a new Werner clathrate and its apohost.
| S-EPMC8477445 | biostudies-literature
Unknown Solid-state interconversions: unique 100?% reversible transformations between the ground and metastable states in single-crystals of a series of nickel(II) nitro complexes.
| S-EPMC4164279 | biostudies-literature
Unknown Reversible ON-OFF switching of single-molecule-magnetism associated with single-crystal-to-single-crystal structural transformation of a decanuclear dysprosium phosphonate.
| S-EPMC6115698 | biostudies-other
Unknown Phase transformation mechanism in lithium manganese nickel oxide revealed by single-crystal hard X-ray microscopy.
| S-EPMC5296648 | biostudies-literature
Unknown Reversible on-off switching of both spin crossover and single-molecule magnet behaviours <i>via</i> a crystal-to-crystal transformation.
| S-EPMC6202758 | biostudies-literature
Unknown Reversible Oxygenation of ?-Amino Acid-Cobalt(II) Complexes.
| S-EPMC4789021 | biostudies-literature
Unknown Crystal structure of a nickel compound comprising two nickel(II) complexes with different ligand environments: [Ni(tren)(H2O)2][Ni(H2O)6](SO4)2.
| S-EPMC7057385 | biostudies-literature
Unknown Shape Preserving Single Crystal to Amorphous to Single Crystal Polymorphic Transformation Is Possible.
| S-EPMC8662720 | biostudies-literature
Unknown Single-Crystal-to-Single-Crystal Cluster Transformation in a Microporous Molybdoarsenate(V)-Metalorganic Framework.
| S-EPMC8493549 | biostudies-literature
Unknown Crystal structures of two nickel compounds comprising neutral Ni<sup>II</sup> hydrazone complexes and di-carb-oxy-lic acids.
| S-EPMC5290543 | biostudies-literature