Dataset Information

Growth Mechanism of Sea Urchin ZnO Nanostructures in Aqueous Solutions and Their Photocatalytic Activity for the Degradation of Organic Dyes.

ABSTRACT: This work reports the development of a fast and simple route for the synthesis of ZnO sea urchin (SU) nanostructures by the formation and assembly of ZnO nanorods under favorable growth conditions in an aqueous solution. The thermal treatment of a basic zinc acetate solution in ethanol results in the formation of aggregated seed clusters consisting of small ZnO nanorods, which were then grown in a precursor solution containing Zn(NO3)2·6H2O and hexamethylenetetramine to assemble the SU structures from the anisotropic ZnO nanorods on the surface of the seed clusters. Each ZnO nanoparticle in the aggregated seed clusters grew sequentially into a ZnO nanorod, and the nanorods were concentric to the core of the clusters yielding the unique SU-like shape. In the presence of a capping agent such as cetyl trimethyl ammonium bromide (CTAB), the aggregated seed clusters were not formed, and the growth of the CTAB-capped ZnO nanorods resulted in separated rods with average aspect ratios of ?10. The SU ZnO nanostructures exhibit a hexagonal wurtzite crystal structure and higher specific surface area (26.9 m2/g) than the CTAB-capped nanorods (17.7 m2/g). The SU ZnO nanostructures show superior photocatalytic efficiency for the degradation of three common organic dyes compared to the ZnO nanorods. The removal efficiencies of indigo carmine, methylene blue, and rhodamine B by the SU nanostructures were 99, 86, and 96%, respectively, after 1 h of UV irradiation. Therefore, the ZnO SU structures have the potential to be a versatile photocatalyst for the photodegradation of organic dyes in industrial wastewater.

SUBMITTER: Kiriarachchi HD

PROVIDER: S-EPMC6714608 | biostudies-literature | 2019 Aug

REPOSITORIES: biostudies-literature

ACCESS DATA

Publications

Growth Mechanism of Sea Urchin ZnO Nanostructures in Aqueous Solutions and Their Photocatalytic Activity for the Degradation of Organic Dyes.

Kiriarachchi Hiran D HD Abouzeid Khaled M KM Bo Longli L El-Shall M Samy MS

ACS omega 20190814 9

This work reports the development of a fast and simple route for the synthesis of ZnO sea urchin (SU) nanostructures by the formation and assembly of ZnO nanorods under favorable growth conditions in an aqueous solution. The thermal treatment of a basic zinc acetate solution in ethanol results in the formation of aggregated seed clusters consisting of small ZnO nanorods, which were then grown in a precursor solution containing Zn(NO3)2·6H2O and hexamethylenetetra ...[more]

PMID: 31497719

Similar Datasets

Project description:Heterogeneous photocatalysis has been considered one of the most effective and efficient techniques to remove organic contaminants from wastewater. The present work was designed to examine the photocatalytic performance of metal (Cu and Ni) doped ZnO nanocomposites in methyl orange (MO) dye degradation under UV light illumination. The wurtzite hexagonal structure was observed for both undoped/doped ZnO and a crystalline size ranging between 8.84 ± 0.71 to 12.91 ± 0.84 nm by X-ray diffraction (XRD) analysis. The scanning electron microscope (SEM) and energy dispersive X-ray (EDX) revealed the irregular spherical shape with particle diameter (34.43 ± 6.03 to 26.43 ± 4.14 nm) and ensured the purity of the individual elemental composition respectively. The chemical bonds (O-H group) and binding energy (1021.8 eV) were identified by Fourier transform infrared (FTIR) and X-ray photoelectron spectroscopy (XPS) results respectively. The bandgap energy was decreased from 3.44 to 3.16 eV when Ni dopant was added to the ZnO lattice. The comparative photocatalytic activity was observed in undoped and doped nanocomposites and found to be 76.31%, 81.95%, 89.30%, and 83.39% for ZnO, Cu/ZnO, Ni/ZnO, and Cu/Ni/ZnO photocatalysts, respectively, for a particular dose (0.210 g) and dye concentration (10 mg L-1) after 180 min illumination of UV light. The photocatalytic performance was increased up to 94.40% with the increase of pH (12.0) whereas reduced (35.12%) with an increase in initial dye concentration (40 mg L-1) using Ni/ZnO nanocomposite. The Ni/ZnO nanocomposite showed excellent reusability and was found 81% after four consecutive cycles. The best-fitted reaction kinetics was followed by pseudo-first-order and found reaction rate constant (0.0117 min-1) using Ni/ZnO nanocomposite. The enhanced photodegradation efficiency was observed due to decreases in bandgap energy and the crystalline size of the photocatalyst. Therefore, Ni/ZnO nanocomposite could be used as an emerging photocatalyst to degrade bio-persistent organic dye compounds from textile wastewater.

Dataset Information

Growth Mechanism of Sea Urchin ZnO Nanostructures in Aqueous Solutions and Their Photocatalytic Activity for the Degradation of Organic Dyes.

Publications

Growth Mechanism of Sea Urchin ZnO Nanostructures in Aqueous Solutions and Their Photocatalytic Activity for the Degradation of Organic Dyes.

Similar Datasets

OmicsDI is part of the ELIXIR infrastructure

Tweets