Ontology highlight
ABSTRACT:
SUBMITTER: Liu S
PROVIDER: S-EPMC6715660 | biostudies-literature | 2019 Aug
REPOSITORIES: biostudies-literature
Nature communications 20190829 1
Covalent organic frameworks with abundant active sites are potential metal-free catalysts for the nitrogen reduction reaction. However, the utilization ratio of active sites is restricted in an actual reaction process due to the limited nitrogen transport. Here, we demonstrate that facilitating the N<sub>2</sub> accessibility to boron-rich covalent organic frameworks through electrochemical excitation can achieve highly efficient nitrogen reduction activity. Simulations show that the boron sites ...[more]