Dataset Information

Assembly of Polyacrylamide-Sodium Alginate-Based Organic-Inorganic Hydrogel with Mechanical and Adsorption Properties.

ABSTRACT: Hydrogels have been widely used in water purification. However, there is not much discussion and comparison about the effects of different nanofillers on the reinforcement and adsorption performances of hydrogels, which can be subjected to rapid water flow and possess strong adsorption ability. In this work, polyacrylamide (PAAM)-sodium alginate (SA) interpenetrating polymer network-structured hydrogels were prepared by in situ polymerization. PAAM formed the first flexible network and SA constructed the second rigid network. Three kinds of inorganic nanoparticles including carbon nanotubes (CNTs), nanoclays (NCs), and nanosilicas (NSs) were incorporated into a PAAM-SA matrix via hydrogen bond. The obtained hydrogels exhibited a macroporous structure with low density (?1.4 g/cm³) and high water content (?83%). Compared with neat PAAM-SA, the hydrogels with inorganic nanoparticles possessed excellent mechanical strengths and elasticities, and the compression strength of PAAM-SA-NS reached up to 1.3 MPa at ? = 60% by adding only 0.036 g NS in a 30 g polymer matrix. However, CNT was the best filler to improve the adsorption capacity owing to its multi-walled hollow nanostructure, and the adsorption capacity of PAAM-SA-CNT was 1.28 times higher than that of PAAM-SA. The prepared hydrogels can be potential candidates for use as absorbents to treat wastewater.

SUBMITTER: Yue Y

PROVIDER: S-EPMC6722572 | biostudies-literature | 2019 Jul

REPOSITORIES: biostudies-literature

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Assembly of Polyacrylamide-Sodium Alginate-Based Organic-Inorganic Hydrogel with Mechanical and Adsorption Properties.

Yue Yiying Y Wang Xianhui X Wu Qinglin Q Han Jingquan J Jiang Jianchun J

Polymers 20190726 8

Hydrogels have been widely used in water purification. However, there is not much discussion and comparison about the effects of different nanofillers on the reinforcement and adsorption performances of hydrogels, which can be subjected to rapid water flow and possess strong adsorption ability. In this work, polyacrylamide (PAAM)-sodium alginate (SA) interpenetrating polymer network-structured hydrogels were prepared by in situ polymerization. PAAM formed the first flexible network and SA constr ...[more]

PMID: 31357415

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Project description:Water pollution by various toxic substances remains a serious environmental problem, especially the occurrence of organic micropollutants including endocrine disruptors, pharmaceutical pollutants and naphthol pollutants. Adsorption process has been an effective method for pollutant removal in wastewater treatment. However, the thermal regeneration process for the most widely used activated carbon is costly and energy-consuming. Therefore, there has been an increasing need to develop alternative low-cost and effective adsorption materials for pollutant removal. Herein, β-cyclodextrin (β-CD), a cheap and versatile material, was modified with methacrylate groups by reacting with methacryloyl chloride, giving an average degree of substitution of 3 per β-CD molecule. β-CD-methacrylate, which could function as a crosslinker, was then copolymerized with acrylamide monomer via free-radical copolymerization to form β-CD-polyacrylamide (β-CD-PAAm) hydrogel. Interestingly, in the structure of the β-CD-PAAm hydrogel, β-CD is not only a functional unit binding pollutant molecules through inclusion complexation, but also a structural unit crosslinking PAAm leading to the formation of the hydrogel 3D networks. Morphological studies showed that β-CD-PAAm gel had larger pore size than the control PAAm gel, which was synthesized using conventional crosslinker instead of β-CD-methacrylate. This was consistent with the higher swelling ratio of β-CD-PAAm gel than that of PAAm gel (29.4 vs. 12.7). In the kinetic adsorption studies, phenolphthalein, a model dye, and bisphenol A, propranolol hydrochloride, and 2-naphthol were used as model pollutants from different classes. The adsorption data for β-CD-PAAm gel fitted well into the pseudo-second-order model. In addition, the thermodynamic studies revealed that β-CD-PAAm gel was able to effectively adsorb the different dye and pollutants at various concentrations, while the control PAAm gel had very low adsorption, confirming that the pollutant removal was due to the inclusion complexation between β-CD units and pollutant molecules. The adsorption isotherms of the different dye and pollutants by the β-CD-PAAm gel fitted well into the Langmuir model. Furthermore, the β-CD-PAAm gel could be easily recycled by soaking in methanol and reused without compromising its performance for five consecutive adsorption/desorption cycles. Therefore, the β-CD-PAAm gel, which combines the advantage of an easy-to-handle hydrogel platform and the effectiveness of adsorption by β-CD units, could be a promising pollutant removal system for wastewater treatment applications.

Dataset Information

Assembly of Polyacrylamide-Sodium Alginate-Based Organic-Inorganic Hydrogel with Mechanical and Adsorption Properties.

Publications

Assembly of Polyacrylamide-Sodium Alginate-Based Organic-Inorganic Hydrogel with Mechanical and Adsorption Properties.

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