Ontology highlight
ABSTRACT:
SUBMITTER: Buttersack T
PROVIDER: S-EPMC6728086 | biostudies-literature | 2019 Feb
REPOSITORIES: biostudies-literature
Buttersack Tillmann T Mason Philip E PE McMullen Ryan S RS Martinek Tomas T Brezina Krystof K Hein Dennis D Ali Hebatallah H Kolbeck Claudia C Schewe Christian C Malerz Sebastian S Winter Bernd B Seidel Robert R Marsalek Ondrej O Jungwirth Pavel P Bradforth Stephen E SE
Journal of the American Chemical Society 20190125 5
Photoelectron spectroscopy of microjets expanded into vacuum allows access to orbital energies for solute or solvent molecules in the liquid phase. Microjets of water, acetonitrile and alcohols have previously been studied; however, it has been unclear whether jets of low temperature molecular solvents could be realized. Here we demonstrate a stable 20 μm jet of liquid ammonia (-60 °C) in a vacuum, which we use to record both valence and core-level band photoelectron spectra using soft X-ray syn ...[more]