Ontology highlight
ABSTRACT:
SUBMITTER: Misra RP
PROVIDER: S-EPMC6750839 | biostudies-literature | 2019 Sep
REPOSITORIES: biostudies-literature
Misra Rahul Prasanna RP de Souza J Pedro JP Blankschtein Daniel D Bazant Martin Z MZ
Langmuir : the ACS journal of surfaces and colloids 20190820 35
Aqueous electrolyte solutions containing multivalent ions exhibit various intriguing properties, including attraction between like-charged colloidal particles, which results from strong ion-ion correlations. In contrast, the classical Derjaguin-Landau-Verwey-Overbeek theory of colloidal stability, based on the Poisson-Boltzmann mean-field theory, always predicts a repulsive electrostatic contribution to the disjoining pressure. Here, we formulate a general theory of surface forces, which predict ...[more]