Unknown

Dataset Information

0

A modified method of separating Tl(I) and Tl(III) in aqueous samples using solid phase extraction.


ABSTRACT: In spite of the development of new measurement techniques in recent years, the rapid and accurate speciation of thallium in environmental aqueous samples remains a challenge. In this context, a novel method of solid phase extraction (SPE), involving the anion exchange resin AG1-X8, is proposed to separate Tl(I) and Tl(III). In the presence of diethylene triamine pentacetate acid (DTPA), Tl(III) and Tl(I) can be separated by selective adsorption of Tl(III)-DTPA onto the resin, Tl(III) is then eluted by a solution of HCl with SO2. The validity of this method was confirmed by assays of standard solutions of Tl(I) and Tl(III). The proposed method is shown to have an outstanding performance even in solutions with a high ratio of Tl(I)/Tl(III), and can be applied to aqueous samples with a high concentration of other electrolytes, which could interfere with the measurement. Portable equipment and reagents make it possible to use the proposed method routinely in the field.

SUBMITTER: Xiao Q 

PROVIDER: S-EPMC6768029 | biostudies-literature | 2018 Dec

REPOSITORIES: biostudies-literature

altmetric image

Publications

A modified method of separating Tl(I) and Tl(III) in aqueous samples using solid phase extraction.

Xiao Qingxiang Q   Rasool Atta A   Xiao Tangfu T   Baveye Philippe C PC  

Chemistry Central journal 20181205 1


In spite of the development of new measurement techniques in recent years, the rapid and accurate speciation of thallium in environmental aqueous samples remains a challenge. In this context, a novel method of solid phase extraction (SPE), involving the anion exchange resin AG1-X8, is proposed to separate Tl(I) and Tl(III). In the presence of diethylene triamine pentacetate acid (DTPA), Tl(III) and Tl(I) can be separated by selective adsorption of Tl(III)-DTPA onto the resin, Tl(III) is then elu  ...[more]

Similar Datasets

| S-EPMC8374489 | biostudies-literature
| S-EPMC6278404 | biostudies-literature
| S-EPMC6017199 | biostudies-literature
| S-EPMC8092778 | biostudies-literature
| S-EPMC5589922 | biostudies-literature
| S-EPMC7533261 | biostudies-literature
| S-EPMC6063368 | biostudies-literature
| S-EPMC9319950 | biostudies-literature
| S-EPMC3970079 | biostudies-literature
| S-EPMC4234481 | biostudies-literature