Engineering Na-Mo-O/Graphene Oxide Composites with Enhanced Electrochemical Performance for Lithium Ion Batteries.

ABSTRACT: Sodium molybdate (Na-Mo-O) wrapped by graphene oxide (GO) composites have been prepared via a simple in-situ precipitation method at room temperature. The composites are mainly constructed with one dimension (1D) ultra-long sodium molybdate nanorods, which are wrapped by the flexible GO. The introduction of GO is expected to not merely provide more active sites for lithium-ions storage, but also improve the charge transfer rate of the electrode. The testing electrochemical performances corroborated the standpoint: The Na-Mo-O/GO composites delivers specific capacities of 718?mAh?g^-1 after 100 cycles at 100?mA?g^-1, and 570?mAh?g^-1 after 500 cycles at a high rate of 500?mA?g^-1; for comparison, the bare Na-Mo-O nanorod shows a severe capacity decay, which deliver only 332?mAh?g^-1 after 100 cycles at 100?mA?g^-1. In view of the cost-efficient and less time-consuming in synthesis, and one-step preparation without further treatment, these Na-Mo-O nanorods/GO composites present potential and prospective anodes for LIBs.

SUBMITTER: Li J 

PROVIDER: S-EPMC6769431 | biostudies-literature | 2019 Oct

REPOSITORIES: biostudies-literature