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Crystal structure of poly[[di-aqua-tetra-?2-cyanido-iron(II)platinum(II)] acetone disolvate].

ABSTRACT: In the title polymeric complex, {[FePt(CN)4(H2O)2]·2C3H6O} n , the FeII cation has an octa-hedral [FeN4O2] geometry being coordinated by two water mol-ecules and four cyanide anions. The Pt cation is located on an inversion centre and has a square-planar coordination environment formed by four cyanide groups. The tetra-cyano-platinate anions bridge the FeII cations to form infinite two-dimensional layers that propagate in the bc plane. Two guest mol-ecules of acetone per FeII are located between the layers. These guest acetone mol-ecules inter-act with the coordinated water mol-ecules by O-H?O hydrogen bonds.

SUBMITTER: Kuzevanova IS

PROVIDER: S-EPMC6775733 | biostudies-literature | 2019 Oct

REPOSITORIES: biostudies-literature

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Crystal structure of poly[[di-aqua-tetra-μ2-cyanido-iron(II)platinum(II)] acetone disolvate].

Kuzevanova Iryna S IS Naumova Dina D DD Terebilenko Kateryna V KV Shova Sergiu S Gural'skiy Il'ya A IA

Acta crystallographica. Section E, Crystallographic communications 20190927 Pt 10

In the title polymeric complex, {[FePt(CN)4(H2O)2]·2C3H6O} n , the FeII cation has an octa-hedral [FeN4O2] geometry being coordinated by two water mol-ecules and four cyanide anions. The Pt cation is located on an inversion centre and has a square-planar coordination environment formed by four cyanide groups. The tetra-cyano-platinate anions bridge the FeII cations to form infinit ...[more]

PMID: 31636989

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