Tetrahedral iron featuring an appended Lewis acid: distinct pathways for the reduction of hydroxylamine and hydrazine.
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ABSTRACT:
SUBMITTER: Kiernicki JJ
PROVIDER: S-EPMC6776999 | biostudies-literature | 2019 Oct
REPOSITORIES: biostudies-literature
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Tetrahedral iron featuring an appended Lewis acid: distinct pathways for the reduction of hydroxylamine and hydrazine.
Kiernicki John J JJ Norwine Emily E EE Zeller Matthias M Szymczak Nathaniel K NK
Chemical communications (Cambridge, England) 20191001 79
We present the preparation of a nitrogen-based bidentate ligand featuring an appended boron Lewis acid as well as its tetrahedral Fe2+ and Zn2+ complexes. These complexes act as platforms for hydrazine and hydroxylamine capture and reduction chemistry. ...[more]
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