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Electrically Conductive Gels Prepared from Syndiotactic Polystyrene and an Ionic Liquid.


ABSTRACT: Syndiotactic polystyrene (SPS) physical gels containing a large amount of the ionic liquid 1-butylpyridinium bromide ([C4py]Br) were systematically prepared and their physical properties were examined in detail. The gels had stable forms for a long time, having storage elastic modulus values of normal gels. They showed nearly the same values of the electrical conductivity (?7 mS/cm) as those of the mixed solutions of [C4py]Br, suggesting that the distribution of [C4py]Br was uniform in these gels and that the charge transportation in these SPS gels was not interrupted by a three-dimensional network of SPS fibrils consisting of the SPS ? crystalline phases.

SUBMITTER: Itagaki H 

PROVIDER: S-EPMC6777124 | biostudies-literature | 2019 Oct

REPOSITORIES: biostudies-literature

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Electrically Conductive Gels Prepared from Syndiotactic Polystyrene and an Ionic Liquid.

Itagaki Hideyuki H   Yoshida Naoto N   Sano Takumi T   Yokoyama Mayu M   Iba Nozomi N   Sugiyama Ryotaro R   Kuroki Masakatsu M  

ACS omega 20190918 14


Syndiotactic polystyrene (SPS) physical gels containing a large amount of the ionic liquid 1-butylpyridinium bromide ([C<sub>4</sub>py]Br) were systematically prepared and their physical properties were examined in detail. The gels had stable forms for a long time, having storage elastic modulus values of normal gels. They showed nearly the same values of the electrical conductivity (∼7 mS/cm) as those of the mixed solutions of [C<sub>4</sub>py]Br, suggesting that the distribution of [C<sub>4</s  ...[more]

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