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Pore Structure and Properties of PEEK Hollow Fiber Membranes: Influence of the Phase Structure Evolution of PEEK/PEI Composite.

ABSTRACT: Poly(ether ether ketone) (PEEK) hollow fiber membranes were successfully prepared from miscible blends of PEEK and polyetherimide (PEI) via thermally-induced phase separation (TIPS) with subsequent extraction of the PEI diluent. The phase structure evolution, extraction kinetics, membrane morphology, pore size distribution and permeability for the hollow fiber membrane were studied in detail. Extraction experiments, differential scanning calorimetry (DSC) and dynamic mechanical thermal analysis (DMA) studies showed that the heat treatment had a significant influence on the two-phase structure of PEEK/PEI, and that it was controlled by the crystallization kinetic of PEEK and the diffusion kinetic of PEI. As the annealing temperature increased, the controlling factor of the phase separation changed from PEEK crystallization to PEI diffusion, and the main distribution of the amorphous PEI chains were changed from the interlamellar region to the interfibrillar or interspherulitic regions of PEEK crystallization. When the annealing temperature increased from 240 °C to 280 °C, the extracted amount of PEI increased from 85.19 to 96.24 wt %, and the pore diameter of PEEK membrane increased from 10.59 to 37.85 nm, while the surface area of the PEEK membrane decreased from 111.9 to 83.69 m²/g. Moreover, the water flux of the PEEK hollow fiber membranes increased from 1.91 × 10^-2 to 1.65 × 10^-1 L h^-1 m^-2 bar^-1 as the annealing temperature increased from 240 °C to 270 °C. The structure and properties of the PEEK hollow fiber membrane can be effectively controlled by regulating heat treatment conditions.

SUBMITTER: Chen G

PROVIDER: S-EPMC6780917 | biostudies-literature |

REPOSITORIES: biostudies-literature

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Project description:Composite membranes play a very important role in the separation, concentration, and purification processes, but especially in membrane reactors and membrane bioreactors. The development of composite membranes has gained momentum especially through the involvement of various nanoparticles, polymeric, oxide, or metal, that have contributed to increasing their reactivity and selectivity. This paper presents the preparation and characterization of an active metal nanoparticle-support polymer type composite membrane, based on osmium nanoparticles obtained in situ on a polypropylene hollow fiber membrane. Osmium nanoparticles are generated from a solution of osmium tetroxide in tert-butyl alcohol by reduction with molecular hydrogen in a contactor with a polypropylene membrane. The composite osmium-polypropylene hollow fiber obtained membranes (Os-PPM) were characterized from the morphological and structural points of view: scanning electron microscopy (SEM), high resolution SEM (HR-SEM), energy dispersive spectroscopy analysis (EDAX), X-ray diffraction analysis (XRD), Fourier transform Infrared (FTIR) spectroscopy, thermal gravimetric analysis, and differential scanning calorimetry (TGA, DSC). The process performance was tested in a redox process of p-nitrophenol and 10-undecylenic (10-undecenoic) acid, as a target substance of biological or biomedical interest, in solutions of lower aliphatic alcohols in a membrane contactor with a prepared composite membrane. The characteristics of osmium nanoparticles-polypropylene hollow fiber membranes open the way to biological and biotechnological applications. These membranes do not contaminate the working environment, operate at relatively low temperatures, provide a large contact area between reactants, allow successive oxidation and reduction operations in the same module, and help to recover the reaction mass by ultrafiltration. The results obtained show that the osmium-polypropylene composite membrane allows the reduction of p-nitrophenol or the oxidation of 10-undecylenic acid, the conversion depending on the concentration in the lower aliphatic alcohol, the nature of the lower aliphatic alcohol, and the oxidant or reducing flow through the membrane contactor.

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Pore Structure and Properties of PEEK Hollow Fiber Membranes: Influence of the Phase Structure Evolution of PEEK/PEI Composite.

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