A New Series of EDOT Based Co-Sensitizers for Enhanced Efficiency of Cocktail DSSC: A Comparative Study of Two Different Anchoring Groups.

ABSTRACT: Herein, we report the design and synthesis strategy of a new class of five EDOT based co-sensitizers (CSGR1-5) by introducing different donors (2,3,4-trimethoxypheny, 2,4-dibutoxyphenyl, and 2,4-difluorophenyl) and anchoring groups (rhodamine-3-acetic acid and cyanoacetic acid) systematically. The synthesized metal-free organic co-sensitizers were employed for cocktail dye-sensitized solar cells along with N749 (black dye). The DSSC devices with a mixture of co-sensitizers (CSGR1-5) and N749 have shown a 7.95%, 8.40%, 7.81%, 6.56% and 6.99% power conversion efficiency (PCE) respectively, which was more than that of single N749 dye PCE (6.18%). Enhanced efficiency could be ascribed to the increased short circuit current (J_sc) and open circuit voltage (V_oc

SUBMITTER: Koyyada G 

PROVIDER: S-EPMC6803997 | biostudies-literature | 2019 Sep

REPOSITORIES: biostudies-literature