Ontology highlight
ABSTRACT:
SUBMITTER: Westphal KR
PROVIDER: S-EPMC6804164 | biostudies-literature | 2019 Sep
REPOSITORIES: biostudies-literature
Westphal Klaus Ringsborg KR Werner Manuela Ilse Helga MIH Nielsen Katrine Amalie Hamborg KAH Sørensen Jens Laurids JL Andrushchenko Valery V Winde Jacob J Hertz Morten M Jensen Mikkel Astrup MA Mortensen Mathilde Lauge ML Bouř Petr P Sondergaard Teis Esben TE Wimmer Reinhard R
Molecules (Basel, Switzerland) 20190926 19
Chemical analyses of <i>Fusarium avenaceum</i> grown on banana medium resulted in eight novel spiroleptosphols, T1, T2 and U-Z (<b>1</b>-<b>8</b>). The structures were elucidated by a combination of high-resolution mass spectrometric data and 1- and 2-D NMR experiments. The relative stereochemistry was assigned by <sup>1</sup>H coupling and NOESY/ROESY experiments. Absolute stereochemistry established for <b>7</b> by vibrational circular dichroism was found analogous to that of the putative poly ...[more]