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Data on synthesis and characterization of sulfonated poly(phenylnorbornene) and polymer electrolyte membranes based on it.

ABSTRACT: This article describes data on preparation of sulfonated hydrogenated poly(phenylnorbornene) with different cations synthesized via sequential ring-opening metathesis polymerization, reduction, homogeneous sulfonation and cation exchange reactions. The data of the characterization of new polymers by nuclear magnetic resonance (1H NMR) spectroscopy, Fourier-transform infrared (FT-IR) spectroscopy and differential scanning calorimetry (DSC) are presented. The effect of imidazolium and 1-methylimidazolium cations, ionic liquid and Zwitter-type ion liquid on ionic conductivities evaluated by impedance spectroscopy. Preparation procedure of polymer electrolyte membrane based on new polymers and Nafion as a blend with polyvinylidene fluoride (PVDF) is given. Scanning electron microscopy images and ionic conductivities of these membrane are presented.

SUBMITTER: Morozov OS 

PROVIDER: S-EPMC6806451 | biostudies-literature | 2019 Dec

REPOSITORIES: biostudies-literature

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Data on synthesis and characterization of sulfonated poly(phenylnorbornene) and polymer electrolyte membranes based on it.

Morozov Oleg S OS   Bulgakov Boris A BA   Ivanchenko Anna V AV   Shachneva Svetlana S SS   Nechausov Sergey S SS   Bermeshev Maxim V MV   Kepman Alexey V AV  

Data in brief 20191007

This article describes data on preparation of sulfonated hydrogenated poly(phenylnorbornene) with different cations synthesized via sequential ring-opening metathesis polymerization, reduction, homogeneous sulfonation and cation exchange reactions. The data of the characterization of new polymers by nuclear magnetic resonance (<sup>1</sup>H NMR) spectroscopy, Fourier-transform infrared (FT-IR) spectroscopy and differential scanning calorimetry (DSC) are presented. The effect of imidazolium and 1  ...[more]

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