ABSTRACT: The present work sets out to 1) evaluate the corrosion-scaling potential of groundwater resources for the industrial sector as well as to 2) examine groundwater chemical parameters for the agricultural sector in the Piranshahr Watershed in the West Azerbaijan province, Iran, using geostatistical analyses and the Wilcox diagram in a GIS environment. A total of 145 spring locations as representatives of groundwater potentiality were recorded by a handheld GPS device and the corrosion and scaling potential states were further scrutinized. The latter was carried out on the basis of examining the chemical parameters at each sample location including alkalinity, pH, temperature, Na+, Ca++, Mg++, TH, HCO3- , Co3-2 , Cl- , SO4-2 , Electrical conductivity, and Total dissolved solids. The corrosion and scaling potential of groundwater was then evaluated by using Langelier saturation index (LSI), Larson-Skold index (LS), Ryznar stability index (RSI), Aggressive index (AI), and Puckorius scaling index (PSI). Also, the groundwater quality state for agriculture was assessed by the Wilcox diagram on the basis of Electrical conductivity and Sodium adsorption ratio parameters. The provided data are beneficial for researchers, policymakers, and authorities for taking pragmatic actions. Also, the compiled data can be used in the context of corrosion/scaling and groundwater quality assessment can be generalized around the world.