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Valorization of coal fired-fly ash for potential heavy metal removal from the single and multi-contaminated system.

ABSTRACT: In this study, adsorption of three different heavy metals i.e. cadmium (Cd (II)), copper (Cu (II)) and nickel (Ni (II)) was carried out in single and multi-contaminated system using coal-fired fly ash (CFFA). Initially, for the single contaminated system, various physical process parameters were selected for optimization by deploying Box-Behnken design of experiments. Further, the evaluation of CFFA for removal of heavy metals in a multi-component system from aqueous solution was performed by employing Plackett-Burman design of experiments with all the three heavy metals at two different levels by varying their initial concentration (10-50 mg L^-1). In both the aforementioned cases, CFFA showed its great potential for heavy metal removal, i.e. single and multi-component system and followed the order: Cu (II) > Ni (II) > Cd (II). Further, FTIR study confirmed the involvement of amide, aldehyde, alkoxy, alkanes, and alkene groups for heavy metal adsorption by CFFA.

SUBMITTER: Kumar M

PROVIDER: S-EPMC6812189 | biostudies-literature | 2019 Oct

REPOSITORIES: biostudies-literature

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Valorization of coal fired-fly ash for potential heavy metal removal from the single and multi-contaminated system.

Kumar Mahendra M Goswami Lalit L Singh Alak Kumar AK Sikandar Mohammad M

Heliyon 20191014 10

In this study, adsorption of three different heavy metals i.e. cadmium (Cd (II)), copper (Cu (II)) and nickel (Ni (II)) was carried out in single and multi-contaminated system using coal-fired fly ash (CFFA). Initially, for the single contaminated system, various physical process parameters were selected for optimization by deploying Box-Behnken design of experiments. Further, the evaluation of CFFA for removal of heavy metals in a multi-component system from aqueous solution was performed by em ...[more]

PMID: 31667403

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Project description:Coal bottom ash (CBA) was modified on the basis of the engineering problems of low resource utilization of CBA and difficulty in treating HMS through alkali activation to synthesize geopolymers and solidify heavy metal-contaminated soil (HMS). The optimal values of geopolymers were selected through response surface methodology. Their mineral compositions, microstructure, and binding energy were determined through X-ray diffraction, X-ray photoelectron spectroscopy, and scanning electron microscopy tests, respectively. The stress-strain curve, the leaching concentration and fraction of heavy metals, and the solidifying mechanism for remolded soil were determined through unconfined compressive strength, leaching toxicity, sequential chemical extraction, and infrared (IR) spectroscopy tests, respectively. Based on these experiments, the following conclusions were presented. The optimum ratios of CBA-based geopolymers were n(Si) : n(Al) = 2.666, n(Na) : n(Al) = 0.687, and n(water) : n(binder) = 2.422. The X-ray curves of the geopolymers were obvious hump-like protuberances at diffraction angles of 20-35° and had a dense amorphous structure on the surface. The maximum binding energies of Si 2p and Al 2p decreased to 101.03 and 72.89 eV, respectively. A 3D network polymerized because of strong geopolymerization. The maximum axial stress of the remolded soil was 104.91% higher than that of the undisturbed soil, and the leaching concentration decreased by more than 45.88%. The leaching toxicity met the requirements of standard GB 5085.3-2007. The proportion of the acid-extractable fraction of heavy metals in the remolded soil decreased, whereas the proportion of residual fraction increased. The stretching vibration of Si-O-Si (Al) and the bending vibration of Si-O-Si appeared in the IR spectrum. The soil particles were completely encapsulated by a hardened geopolymer structure, thereby forming a multilayer space-skeleton barrier structure that could greatly improve the mechanical properties.

Project description:Geopolymers are inorganic polymers formed from the alkaline activation of amorphous alumino-silicate materials resulting in a three-dimensional polymeric network. As a class of materials, it is seen to have the potential of replacing ordinary Portland cement (OPC), which for more than a hundred years has been the binder of choice for structural and building applications. Geopolymers have emerged as a sustainable option vis-à-vis OPC for three reasons: (1) their technical properties are comparable if not better; (2) they can be produced from industrial wastes; and (3) within reasonable constraints, their production requires less energy and emits significantly less CO₂. In the Philippines, the use of coal ash, as the alumina- and silica- rich geopolymer precursor, is being considered as one of the options for sustainable management of coal ash generation from coal-fired power plants. However, most geopolymer mixes (and the prevalent blended OPC) use only coal fly ash. The coal bottom ash, having very few applications, remains relegated to dumpsites. Rice hull ash, from biomass-fired plants, is another silica-rich geopolymer precursor material from another significantly produced waste in the country with only minimal utilization. In this study, geopolymer samples were formed from the mixture of coal ash, using both coal fly ash (CFA) and coal bottom ash (CBA), and rice hull ash (RHA). The raw materials used for the geopolymerization process were characterized using X-ray fluorescence spectroscopy (XRF) for elemental and X-ray diffraction (XRD) for mineralogical composition. The raw materials' thermal stability and loss on ignition (LOI) were determined using thermogravimetric analysis (TGA) and reactivity via dissolution tests and inductively-coupled plasma mass spectrometry (ICP) analysis. The mechanical, thermal and microstructural properties of the geopolymers formed were analyzed using compression tests, Fourier transform infra-red spectroscopy (FTIR), scanning electron microscopy (SEM) and thermogravimetric analysis (TGA). Using a Scheffé-based mixture design, targeting applications with low thermal conductivity, light weight and moderate strength and allowing for a maximum of five percent by mass of rice hull ash in consideration of the waste utilization of all three components, it has been determined that an 85-10-5 by weight ratio of CFA-CBA-RHA activated with 80-20 by mass ratio of 12 M NaOH and sodium silicate (55% H₂O, modulus = 3) produced geopolymers with a compressive strength of 18.5 MPa, a volumetric weight of 1660 kg/m³ and a thermal conductivity of 0.457 W/m-°C at 28-day curing when pre-cured at 80 °C for 24 h. For this study, the estimates of embodied energy and CO₂ were all below 1.7 MJ/kg and 0.12 kg CO₂/kg, respectively.

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Valorization of coal fired-fly ash for potential heavy metal removal from the single and multi-contaminated system.

Publications

Valorization of coal fired-fly ash for potential heavy metal removal from the single and multi-contaminated system.

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