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Improved Morphological and Localized Surface Plasmon Resonance (LSPR) Properties of Fully Alloyed Bimetallic AgPt and Monometallic Pt NPs Via the One-Step Solid-State Dewetting (SSD) of the Ag/Pt Bilayers.

ABSTRACT: Multi-metallic alloy nanoparticles (NPs) can offer a promising route for the integration of multi-functional elements by the adaptation of advantageous individual NP properties and thus can exhibit the multi-functional dynamic properties arisen from the electronic heterogeneity as well as configurational diversity. The integration of Pt-based metallic alloy NPs are imperative in the catalytic, sensing, and energy applications; however, it usually suffers from the difficulty in the fabrication of morphologically well-structured and elementally well-alloyed NPs, which yields poor plasmonic responses. In this work, the improved morphological and localized surface plasmon resonance (LSPR) properties of fully alloyed bimetallic AgPt and monometallic Pt NPs are demonstrated on sapphire (0001) via the one-step solid-state dewetting (SSD) of the Ag/Pt bilayers. In a sharp contrast to the previous studies of pure Pt NPs, the surface morphology of the resulting AgPt and Pt NPs in this work are significantly improved such that they possess larger size, increased interparticle gaps, and improved uniformity. The intermixing of Ag and Pt atoms, AgPt alloy formation, and concurrent sublimation of Ag atoms plays the major roles in the fabrication of bimetallic AgPt and monometallic Pt NPs along with the enhanced global diffusion and energy minimization of NP system. The fabricated AgPt and Pt NPs show much-enhanced LSPR responses as compared to the pure Pt NPs in the previous studies, and the excitation of dipolar, quadrupolar, multipolar and higher-order resonance modes is realized depending upon the size, configuration, and elemental compositions. The LSPR peaks demonstrate drastic alteration along with the evolution of AgPt and Pt NPs, i.e., the resonance peaks are shifted and enhanced by the variation of size and Ag content.

SUBMITTER: Kunwar S

PROVIDER: S-EPMC6813404 | biostudies-literature | 2019 Oct

REPOSITORIES: biostudies-literature

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Improved Morphological and Localized Surface Plasmon Resonance (LSPR) Properties of Fully Alloyed Bimetallic AgPt and Monometallic Pt NPs Via the One-Step Solid-State Dewetting (SSD) of the Ag/Pt Bilayers.

Kunwar Sundar S Pandey Puran P Pandit Sanchaya S Sui Mao M Lee Jihoon J Lee Jihoon J

Nanoscale research letters 20191024 1

Multi-metallic alloy nanoparticles (NPs) can offer a promising route for the integration of multi-functional elements by the adaptation of advantageous individual NP properties and thus can exhibit the multi-functional dynamic properties arisen from the electronic heterogeneity as well as configurational diversity. The integration of Pt-based metallic alloy NPs are imperative in the catalytic, sensing, and energy applications; however, it usually suffers from the difficulty in the fabrication of ...[more]

PMID: 31650295

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Project description:Multi-metallic alloy nanoparticles (NPs) can offer tunable or modifiable localized surface plasmon resonance (LSPR) properties depending upon their configurational and elemental alterations, which can be utilized in various applications, that is, in photon energy harvesting, optical sensing, biomedical imaging, photocatalysis, and spectroscopy. In this work, a systematic investigation on the morphological and LSPR properties of multi-metallic alloy NPs incorporating Ag, Au, Pd, and Pt is presented on c-plane sapphire (0001). The resulting NPs exhibit much enhanced and tunable LSPR bands in the UV-VIS wavelength as compared to the previously reported mono-metallic NPs based on the considerable improvement in size and shape of nanostructures along with the electronic heterogeneity. Solid-state dewetting of sputtered bilayers (Ag/Pt), tri-layers (Ag/Au/Pt), and quad-layers (Ag/Au/Pd/Pt) is employed to demonstrate a wide variety of configurations, sizes, densities, and elemental compositions of Pt, AgPt, AuPt, AgAuPt, AgAuPt, and AgAuPdPt NPs by the systematic control of annealing temperature and deposition schemes. The distinct morphology and elemental composition of surface nanostructures are obtained by means of surface diffusion, intermixing, and surface/interface energy minimization along with the applied thermal energy. In addition, the sublimation of Ag atoms from the alloy nanostructure matrix significantly influences the structural, elemental, and thus optical properties of NPs by reducing the average size and Ag percentage in the alloy NPs. Based on the specific size, shape, and elemental composition of NPs, the excitation of LSPR is correlated to the dipolar, quadrupolar, multi-polar, and higher order (HO) modes along with the finite difference time domain simulation of local electric-field. The LSPR intensity is generally stronger with a higher percentage of Ag atoms in the alloy NPs and gradually diminished by the sublimation loss. However, even the mono-metallic and alloy NPs without Ag exhibited significantly improved and dynamic nature of plasmonic bands in the UV and VIS wavelength.

Dataset Information

Improved Morphological and Localized Surface Plasmon Resonance (LSPR) Properties of Fully Alloyed Bimetallic AgPt and Monometallic Pt NPs Via the One-Step Solid-State Dewetting (SSD) of the Ag/Pt Bilayers.

Publications

Improved Morphological and Localized Surface Plasmon Resonance (LSPR) Properties of Fully Alloyed Bimetallic AgPt and Monometallic Pt NPs Via the One-Step Solid-State Dewetting (SSD) of the Ag/Pt Bilayers.

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