Dynamic oxygen adsorption on single-atomic Ruthenium catalyst with high performance for acidic oxygen evolution reaction.

ABSTRACT: Achieving active and stable oxygen evolution reaction (OER) in acid media based on single-atom catalysts is highly promising for cost-effective and sustainable energy supply in proton electrolyte membrane electrolyzers. Here, we report an atomically dispersed Ru₁-N₄ site anchored on nitrogen-carbon support (Ru-N-C) as an efficient and durable electrocatalyst for acidic OER. The single-atom Ru-N-C catalyst delivers an exceptionally intrinsic activity, reaching a mass activity as high as 3571?A g_metal^-1 and turnover frequency of 3348 O₂ h^-1 with a low overpotential of 267?mV at a current density of 10?mA?cm^-2. The catalyst shows no evident deactivation or decomposition after 30-hour operation in acidic environment. Operando synchrotron radiation X-ray absorption spectroscopy and infrared spectroscopy identify the dynamic adsorption of single oxygen atom on Ru site under working potentials, and theoretical calculations demonstrate that the O-Ru₁-N₄ site is responsible for the high OER activity and stability.

SUBMITTER: Cao L 

PROVIDER: S-EPMC6813412 | biostudies-literature | 2019 Oct

REPOSITORIES: biostudies-literature