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Synthesis of Mo2C and W2C Nanoparticle Electrocatalysts for the Efficient Hydrogen Evolution Reaction in Alkali and Acid Electrolytes.

ABSTRACT: The synthesis of low cost, high efficacy, and durable hydrogen evolution electrocatalysts from the non-noble metal group is a major challenge. Herein, we establish a simple and inexpensive chemical reduction method for producing molybdenum carbide (Mo2C) and tungsten carbide (W2C) nanoparticles that are efficient electrocatalysts in alkali and acid electrolytes for hydrogen evolution reactions (HER). Mo2C exhibits outstanding electrocatalytic behavior with an overpotential of -134 mV in acid medium and of -116 mV in alkaline medium, while W2C nanoparticles require an overpotential of -173 mV in acidic medium and -130 mV in alkaline medium to attain a current density of 10 mA cm-2. The observed results prove the capability of high- and low-pH active electrocatalysts of Mo2C and W2C nanoparticles to be efficient systems for hydrogen production through HER water electrolysis.

SUBMITTER: Hussain S

PROVIDER: S-EPMC6823202 | biostudies-literature | 2019

REPOSITORIES: biostudies-literature

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Synthesis of Mo2C and W2C Nanoparticle Electrocatalysts for the Efficient Hydrogen Evolution Reaction in Alkali and Acid Electrolytes.

Hussain Sajjad S Vikraman Dhanasekaran D Feroze Asad A Song Wooseok W An Ki-Seok KS Kim Hyun-Seok HS Chun Seung-Hyun SH Jung Jongwan J

Frontiers in chemistry 20191025

The synthesis of low cost, high efficacy, and durable hydrogen evolution electrocatalysts from the non-noble metal group is a major challenge. Herein, we establish a simple and inexpensive chemical reduction method for producing molybdenum carbide (Mo2C) and tungsten carbide (W2C) nanoparticles that are efficient electrocatalysts in alkali and acid electrolytes for hydrogen evolution reactions (HER). Mo2C exhibits outstanding electrocatalytic behavior with an ove ...[more]

PMID: 31709239

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Project description:The design and fabrication of inexpensive highly efficient electrocatalysts for the production of hydrogen via the hydrogen evolution reaction (HER) underpin a plethora of emerging clean energy technologies. Herein, we report the fabrication of highly efficient electrocatalysts for the HER based on magnetron-sputtered MoS2 onto a nanocarbon support, termed MoS2/C. Magnetron sputtering time is explored as a function of its physiochemical composition and HER performance; increased sputtering times give rise to materials with differing compositions, i.e., Mo4+ to Mo6+ and associated S anions (sulfide, elemental, and sulfate), and improved HER outputs. An optimized sputtering time of 45 min was used to fabricate the MoS2/C material. This gave rise to an optimal HER performance with regard to its HER onset potential, achievable current, and Tafel value, which were -0.44 (vs saturated calomel electrode (SCE)), -1.45 mV s-1, and 43 mV dec-1, respectively, which has the highest composition of Mo4+ and sulfide (MoS2). Electrochemical testing toward the HER via drop casting MoS2/C upon screen-printed electrodes (SPEs) to electrically wire the nanomaterial is found to be mass coverage dependent, where the current density increases up to a critical mass (ca. 50 μg cm-2), after which a plateau is observed. To allow for a translation of the bespoke fabricated MoS2/C from laboratory to new industrial applications, MoS2/C was incorporated into the bulk ink utilized in the fabrication of SPEs (denoted as MoS2/C-SPE), thus allowing for improved electrical wiring to the MoS2/C and resulting in the production of scalable and reproducible electrocatalytic platforms. The MoS2/C-SPEs displayed far greater HER catalysis with a 450 mV reduction in the HER onset potential and a 1.70 mA cm-2 increase in the achievable current density (recorded at -0.75 V (vs SCE)), compared to a bare/unmodified graphitic SPE. The approach of using magnetron sputtering to modify carbon with MoS2 facilitates the production of mass-producible, stable, and effective electrode materials for possible use in electrolyzers, which are cost competitive to Pt and mitigate the need to use time-consuming and low-yield exfoliation techniques typically used to fabricate pristine MoS2.

Dataset Information

Synthesis of Mo2C and W2C Nanoparticle Electrocatalysts for the Efficient Hydrogen Evolution Reaction in Alkali and Acid Electrolytes.

Publications

Synthesis of Mo<sub>2</sub>C and W<sub>2</sub>C Nanoparticle Electrocatalysts for the Efficient Hydrogen Evolution Reaction in Alkali and Acid Electrolytes.

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